The geometrical phase transition in non-linear hydrogen bonding systems
文献类型:期刊论文
作者 | H. J. Wang ; X. Z. Hong ; X. W. Ba |
刊名 | Chemical Physics Letters
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出版日期 | 2005 |
卷号 | 413期号:1-3页码:221-225 |
关键词 | liquid water thermoreversible gelation temperature networks methanol fluids thermodynamics cooperativity dependence polymers |
ISSN号 | 0009-2614 |
中文摘要 | Hydrogen bonding (HB) in a system consisting of A(a)D(d) type molecules is studied by two different statistical ways that are demonstrated to be consistent with each other. The free energies of the sol and gel phases in both pregel and postgel regimes are further obtained. It is shown that the sol-gel phase transition in a non-linear HB system is a geometrical phase transition, and for describing this phase transition, the scaling laws satisfied by the moments, the radii of gyration and the gel free energy near the critical point are obtained. (c) 2005 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35072] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. J. Wang,X. Z. Hong,X. W. Ba. The geometrical phase transition in non-linear hydrogen bonding systems[J]. Chemical Physics Letters,2005,413(1-3):221-225. |
APA | H. J. Wang,X. Z. Hong,&X. W. Ba.(2005).The geometrical phase transition in non-linear hydrogen bonding systems.Chemical Physics Letters,413(1-3),221-225. |
MLA | H. J. Wang,et al."The geometrical phase transition in non-linear hydrogen bonding systems".Chemical Physics Letters 413.1-3(2005):221-225. |
入库方式: OAI收割
来源:金属研究所
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