Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating
文献类型:期刊论文
作者 | Z. Y. Wang ; E. H. Han ; W. Ke |
刊名 | Progress in Organic Coatings
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出版日期 | 2005 |
卷号 | 53期号:1页码:29-37 |
关键词 | APP/PER/EN coating Char formation intumescent flame-retardant coating nano-size magnesium aluminum-layered double hydroxides (nano-LDHs) flame-retardant nano-concentrates ammonium polyphosphate surface polypropylene polyurethane formulations nanofillers |
ISSN号 | 0300-9440 |
中文摘要 | Flame-retardant nano-coatings were prepared by adding flame-retardant nano-concentrates to APP/PER/EN coating. Dispersion morphology and stability principle of nano-size magnesium aluminum-layered double hydroxides (nano-LDHs) have been studied by using transmission electron microscopy (TEM). Relation of added amount of nano-concentrates in flame-retardant coating to flame-retardant properties for APP/PER/EN system has been studied by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), differential thermal analysis (DTA), thermogravimetry (IG) and fire protection test. It was indicated that nano-LDHs could catalyze the esterification reaction between ammonium polyphosphate and pentaerythritol, and IPN network formed by nano-size thermal-decomposed products of LDH could efficiently enhance char formation and structure of char layer. Only specific content (1.5%) of nano-LDHs in flame-retardant coating could efficiently improve its char layer structure and fire-resistant properties. Nano-LDHs (1.5%) greatly improve mechanical properties (bonding strength, bending resistance and resistance to freeze-thaw cycle) of flame-retardant coating. (c) 2005 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35103] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Z. Y. Wang,E. H. Han,W. Ke. Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating[J]. Progress in Organic Coatings,2005,53(1):29-37. |
APA | Z. Y. Wang,E. H. Han,&W. Ke.(2005).Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating.Progress in Organic Coatings,53(1),29-37. |
MLA | Z. Y. Wang,et al."Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating".Progress in Organic Coatings 53.1(2005):29-37. |
入库方式: OAI收割
来源:金属研究所
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