X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys
文献类型：期刊论文
| 作者 | J. Xu ; X. G. Li ; X. B. Liu ; C. F. Dong ; N. Deem ; E. Barbero |
| 刊名 | Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science
 |
| 出版日期 | 2005 |
| 卷号 | 36A期号:8页码:2175-2190 |
| 关键词 | lead-acid-batteries corrosion layers tin plate |
| ISSN号 | 1073-5623 |
| 中文摘要 | In this article, passivated Pb-Sn and Pb-Sb alloys with different compositions were studied by X-ray photoelectron spectroscopy (XPS). The passive films were found to have a double-layer structure. Both Sri and Sb were found to play an important role during the growth of passive film, which resulted in different compositions of passive films. The Pb oxides, Pb sulfate, Sn/Sb oxides, and Pb-Sn/Sb complex oxides (PbOx-Sn1-xO2, PbSb2O6) were present in the passive films. Both Sri and Sb facilitated PbOx (1 < x < 2) formation, which was considered to be very helpful to optimize the conductivity of passive films. It was also shown that the positions of peak signals of alloying Sn/Sb, Pb, and O were almost fixed, even though the contents of alloying Sn/Sb oxides were quite different in different specimens. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35159]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. Xu,X. G. Li,X. B. Liu,et al. X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys[J]. Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,2005,36A(8):2175-2190. |
| APA | J. Xu,X. G. Li,X. B. Liu,C. F. Dong,N. Deem,&E. Barbero.(2005).X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys.Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,36A(8),2175-2190. |
| MLA | J. Xu,et al."X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys".Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science 36A.8(2005):2175-2190. |
入库方式： OAI收割
来源：金属研究所
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