Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds
文献类型：期刊论文
| 作者 | W. H. Yang ; J. M. Wang ; Z. N. Yang ; T. Pan ; J. Q. Zhang |
| 刊名 | Chinese Journal of Chemical Physics
 |
| 出版日期 | 2005 |
| 卷号 | 18期号:1页码:105-112 |
| 关键词 | Fe(VI) compounds synthesis analysis stability ab initio super-iron battery ferrate potassium electrode bafeo4 |
| ISSN号 | 1003-7713 |
| 中文摘要 | In order to understand the physical properties and electrochemical performance of several kinds of Fe(VI) compounds, K2FeO4, BaFeO4, SrFeO4 and K2Sr( FeO4)(2) were synthesized by a chemical method. The appearance, structure, solubility and discharge performance of the four kinds of ferrates were investigated. Studies show that BaFeO4 has better discharge performance. However, it has been found out that other ferrates except for K2FeO4 are unstable. They decompose in dry environment. The quantum ab initio calculation was used to compare the polarization effects of positive ions on FeO42-. Results show that the Fe(VI) compounds become less stable with the increase of the polarization effects. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35172]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. H. Yang,J. M. Wang,Z. N. Yang,et al. Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds[J]. Chinese Journal of Chemical Physics,2005,18(1):105-112. |
| APA | W. H. Yang,J. M. Wang,Z. N. Yang,T. Pan,&J. Q. Zhang.(2005).Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds.Chinese Journal of Chemical Physics,18(1),105-112. |
| MLA | W. H. Yang,et al."Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds".Chinese Journal of Chemical Physics 18.1(2005):105-112. |
入库方式： OAI收割
来源：金属研究所
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