Electrochemical activities of IrO2 electrodes in small organic molecules containing aqueous solutions
文献类型：期刊论文
| 作者 | J. M. Hu ; J. Q. Zhang ; J. T. Zhang ; C. N. Cao |
| 刊名 | Acta Physico-Chimica Sinica
 |
| 出版日期 | 2004 |
| 卷号 | 20期号:7页码:740-744 |
| 关键词 | IrO2 electrode methanol formic acid formaldehyde electrochemical activity oxygen-evolving electrodes long service life iro2+ta2o5 anodes surface characterization methanol oxidation catalytic-activity oxide electrodes sulfuric-acid evolution impedance |
| ISSN号 | 1000-6818 |
| 中文摘要 | The electrochemical activities of Ti based IrO2 active coating electrodes in Na2SO4 aqueous solutions containing methanol, formic acid and formaldehyde, respectively, were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The activity was quantitatively characterized by the double-layer capacitance, C-dl. The results showed that in comporison with that in H2SO4 electrolyte the electrode activity in Na2SO4 solution with the same concentration declines dramatically. The active surface area of the electrodes was also found to decrease in the presence of these small organic moleculars. It was found that the electrooxidation of organic compounds can take place in a wide potential region, but with a slow reaction rate. The organic oxidation is facilitated by the oxygen evolution on this type of electrode. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35373]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. M. Hu,J. Q. Zhang,J. T. Zhang,et al. Electrochemical activities of IrO2 electrodes in small organic molecules containing aqueous solutions[J]. Acta Physico-Chimica Sinica,2004,20(7):740-744. |
| APA | J. M. Hu,J. Q. Zhang,J. T. Zhang,&C. N. Cao.(2004).Electrochemical activities of IrO2 electrodes in small organic molecules containing aqueous solutions.Acta Physico-Chimica Sinica,20(7),740-744. |
| MLA | J. M. Hu,et al."Electrochemical activities of IrO2 electrodes in small organic molecules containing aqueous solutions".Acta Physico-Chimica Sinica 20.7(2004):740-744. |
入库方式： OAI收割
来源：金属研究所
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