Chaotic, mixed-mode and periodic oscillations during the electro-oxidation of copper in trichloroacetic acid
文献类型：期刊论文
| 作者 | L. A. Li ; S. H. Chen ; H. T. Wu ; H. T. Cui |
| 刊名 | Journal of the Serbian Chemical Society
 |
| 出版日期 | 2004 |
| 卷号 | 69期号:1页码:33-42 |
| 关键词 | current oscillations copper trichloroacctic acid anodic-dissolution chloride solution phosphoric-acid electrochemical reaction acetate buffer film formation electrodissolution iron electrode behavior |
| ISSN号 | 0352-5139 |
| 中文摘要 | The current oscillations of a copper electrode in trichloroacetic acid solutions were studied in this paper. The Cu/CCl3COOH System is a new electrochemical oscillator showing rich dynamic behaviour on two controllable parameters: the trichloroacetic acid concentration (c(Cl3COOH)) and the imposed potential (E). Phase trajectories were reconstructed from time series using time delay methods in order that the complex oscillations could be analyzed. Five kinds of oscillations. periodic and quasipefiodic. mixed-mode. aperiodic. small amplitude and chaotic current oscillations, were observed. The EDS (energy dispersive spectroscopy) technique was used to analyze the elemental composition of the film formed on the surface of the copper electrode after the current oscillations. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35408]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | L. A. Li,S. H. Chen,H. T. Wu,et al. Chaotic, mixed-mode and periodic oscillations during the electro-oxidation of copper in trichloroacetic acid[J]. Journal of the Serbian Chemical Society,2004,69(1):33-42. |
| APA | L. A. Li,S. H. Chen,H. T. Wu,&H. T. Cui.(2004).Chaotic, mixed-mode and periodic oscillations during the electro-oxidation of copper in trichloroacetic acid.Journal of the Serbian Chemical Society,69(1),33-42. |
| MLA | L. A. Li,et al."Chaotic, mixed-mode and periodic oscillations during the electro-oxidation of copper in trichloroacetic acid".Journal of the Serbian Chemical Society 69.1(2004):33-42. |
入库方式： OAI收割
来源：金属研究所
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