Energy spectra of the tunable laser crystal Gd3Ga5O12 : Cr3+ and their pressure-induced shifts
文献类型:期刊论文
作者 | D. P. Ma |
刊名 | Communications in Theoretical Physics
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出版日期 | 2004 |
卷号 | 41期号:1页码:141-150 |
关键词 | high-pressure effect line shift spin-orbit interaction electron-phonon interaction d-orbital coupling between t(2)(2)(T-3(1))e(4)T(2) and t(2)(3) E-2 tunable laser crystal theoretical calculations r-1 line gsgg-cr3+ garnet spectroscopy ruby gd3sc2ga3o12 temperature cr-3+ |
ISSN号 | 0253-6102 |
中文摘要 | By means of both the theory for pressure-induced shifts (PS) of energy spectra and the theory for shifts of energy spectra due to electron-phonon interaction (EPI), at 300 K, the 'pure electronic' contributions and the contributions from EPI to R-1 line, R-2 line, and U band of GGG:Cr3+ as well as their PS have been calculated, respectively. The total calculated results are in good agreement with all the experimental data. Their physical origins have been explained. It is found that the mixing-degree of \t(2)(2)(T-3(1))e(4)T(2)] and \t(2)(3 2)E] base-wavefunctions in the wavefunctions of R-1 level of GGG:Cr3+ is considerable under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role for PS of R-1 line or R-2 line. At 300 K, both the temperature-independent contribution to R-1 line (or R-2 line or U band) from EPI and the temperature-dependent one are important. The remarkable difference between pressure-dependent behaviors of PS of R-1 lines of GGG:Cr3+ and GSGG:Cr3+ results from the differences of their microscopic properties. The features of emission spectra of GGG:Cr3+ at various pressures have satisfactorily been explained. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35492] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | D. P. Ma. Energy spectra of the tunable laser crystal Gd3Ga5O12 : Cr3+ and their pressure-induced shifts[J]. Communications in Theoretical Physics,2004,41(1):141-150. |
APA | D. P. Ma.(2004).Energy spectra of the tunable laser crystal Gd3Ga5O12 : Cr3+ and their pressure-induced shifts.Communications in Theoretical Physics,41(1),141-150. |
MLA | D. P. Ma."Energy spectra of the tunable laser crystal Gd3Ga5O12 : Cr3+ and their pressure-induced shifts".Communications in Theoretical Physics 41.1(2004):141-150. |
入库方式: OAI收割
来源:金属研究所
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