Oxidation of two ternary Fe-Cu-5 at.% al alloys in 1 atm of pure O-2 at 800 degrees C
文献类型:期刊论文
作者 | J. H. Xiang ; Y. Niu ; F. Gesmundo |
刊名 | Oxidation of Metals
![]() |
出版日期 | 2004 |
卷号 | 61期号:5-6页码:403-421 |
关键词 | ternary alloys iron-copper base oxidation aluminium effect low oxidant pressures cu-cr alloys forming insoluble oxides 2-phase binary-alloys internal oxidation external oxidation air oxidation approximate analysis h-2-h2s mixtures ag alloys |
ISSN号 | 0030-770X |
中文摘要 | The oxidation of two two-phase ternary Fe - Cu - Al alloys containing about 5 at.% aluminium, one Fe-rich and one Cu-rich, has been studied at 800degreesC under 1 atm O-2. The Fe- rich alloy (Fe - 15Cu - 5Al) shows two parabolic stages, with a large decrease of the parabolic rate constant after about 2 hr. The presence of 5 at.% Al reduces significantly the oxidation rate of this alloy with respect to a binary Fe- Cu alloy of similar composition by forming an external alumina scale. Moreover, the addition of 15 at.% Cu is able to reduce the critical aluminium content needed to form alumina scales with respect to binary Fe - Al alloys. On the contrary, the Cu-rich Fe - 85Cu-5Al alloy presents a single parabolic stage and forms a thick and porous external scale composed of an outermost layer of copper oxides and an inner region containing a mixture of copper and Fe - Al oxides, coupled to the internal oxidation of iron and aluminium. As a result, the oxidation of the Cu-rich ternary alloy at 800degreesC is much faster than that of the Fe- rich ternary alloy. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35648] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. H. Xiang,Y. Niu,F. Gesmundo. Oxidation of two ternary Fe-Cu-5 at.% al alloys in 1 atm of pure O-2 at 800 degrees C[J]. Oxidation of Metals,2004,61(5-6):403-421. |
APA | J. H. Xiang,Y. Niu,&F. Gesmundo.(2004).Oxidation of two ternary Fe-Cu-5 at.% al alloys in 1 atm of pure O-2 at 800 degrees C.Oxidation of Metals,61(5-6),403-421. |
MLA | J. H. Xiang,et al."Oxidation of two ternary Fe-Cu-5 at.% al alloys in 1 atm of pure O-2 at 800 degrees C".Oxidation of Metals 61.5-6(2004):403-421. |
入库方式: OAI收割
来源:金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。