The effects of applied electric fields on the EPR spectra of Fe3+ ion in tetragonal SrTiO3 crystal
文献类型:期刊论文
作者 | W. C. Zheng ; S. Tang ; X. X. Wu |
刊名 | Journal of Magnetism and Magnetic Materials
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出版日期 | 2004 |
卷号 | 283期号:2-3页码:276-281 |
关键词 | electron paramagnetic resonance electric-field effect crystal field ligand field SrTiO3 : Fe3(+) covalency contribution state temperature resonance phase srcl2 ktao3 |
ISSN号 | 0304-8853 |
中文摘要 | The electric-field-induced zero-field splittings for Fe3+ in tetragonal phase of SrTiO3 are studied from the microscopic mechanisms and the empirical superposition model. From the studies, it is found that the induced zero-field splittings can be reasonably explained by considering suitable Fe3+ displacements along the electric-field direction in the tetragonal (FeO6)(9-) groups in SrTiO3:Fe3+. The electric-field-induced Fe3+ displacements obtained by the above two methods are close to each other and they are also comparable with those obtained from the force-balance equation. The strong temperature dependences of electric-field-induced zero-field splitting and hence of Fe3+ displacement can be attributed mainly to the strong temperature dependence of dielectric constant of SrTiO3 crystal. (C) 2004 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35757] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,S. Tang,X. X. Wu. The effects of applied electric fields on the EPR spectra of Fe3+ ion in tetragonal SrTiO3 crystal[J]. Journal of Magnetism and Magnetic Materials,2004,283(2-3):276-281. |
APA | W. C. Zheng,S. Tang,&X. X. Wu.(2004).The effects of applied electric fields on the EPR spectra of Fe3+ ion in tetragonal SrTiO3 crystal.Journal of Magnetism and Magnetic Materials,283(2-3),276-281. |
MLA | W. C. Zheng,et al."The effects of applied electric fields on the EPR spectra of Fe3+ ion in tetragonal SrTiO3 crystal".Journal of Magnetism and Magnetic Materials 283.2-3(2004):276-281. |
入库方式: OAI收割
来源:金属研究所
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