Effects of barium on the performance of secondary alkaline zinc electrode
文献类型:期刊论文
作者 | Y. Zheng ; J. M. Wang ; H. Chen ; J. Q. Zhang ; C. N. Cao |
刊名 | Materials Chemistry and Physics
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出版日期 | 2004 |
卷号 | 84期号:1页码:99-106 |
关键词 | barium zincate pasted zinc electrode zinc oxide EIS ni-zn cells impedance plane displays zn/niooh cells cycle life stability conditions calcium hydroxide steady-state silver-zinc batteries additives |
ISSN号 | 0254-0584 |
中文摘要 | The active material of secondary alkaline zinc electrode with barium additives was prepared by a chemical reaction method and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical performance of various pasted Zn electrodes was investigated by cyclic voltammetry, charge/discharge method and electrochemical impedance spectroscopy (EIS). The addition of barium can synthesize a compound barium zincate with the molecular structure of BaZn(OH)(4)(.)xH(2)O, which turns into another molecular structure of BaZnO2 after heat treatment, and improve the discharge performance. The EIS of the various Zn electrodes show two time constants besides diffusion impedance including a state variable representing the covering degree of ZnO on the electrode surface. (C) 2003 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/35763] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. Zheng,J. M. Wang,H. Chen,et al. Effects of barium on the performance of secondary alkaline zinc electrode[J]. Materials Chemistry and Physics,2004,84(1):99-106. |
APA | Y. Zheng,J. M. Wang,H. Chen,J. Q. Zhang,&C. N. Cao.(2004).Effects of barium on the performance of secondary alkaline zinc electrode.Materials Chemistry and Physics,84(1),99-106. |
MLA | Y. Zheng,et al."Effects of barium on the performance of secondary alkaline zinc electrode".Materials Chemistry and Physics 84.1(2004):99-106. |
入库方式: OAI收割
来源:金属研究所
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