Physicochemical properties and electrochemical performance of Al-substituted alpha-Ni-(OH)(2) with additives for Ni-metal hydride batteries
文献类型：期刊论文
| 作者 | H. Chen ; J. M. Wang ; T. Pan ; Y. L. Zhao ; J. Q. Zhang ; C. N. Cao |
| 刊名 | Journal of the Electrochemical Society
 |
| 出版日期 | 2003 |
| 卷号 | 150期号:11页码:A1399-A1404 |
| 关键词 | rechargeable alkaline batteries nickel-hydroxide electrodes layered double hydroxide positive electrode secondary cells active material behavior cobalt zinc |
| ISSN号 | 0013-4651 |
| 中文摘要 | Al-substituted alpha-Ni(OH)(2) coprecipitated with the additives Mg2+ and Co2+ was prepared by a complexation-coprecipitation method. The physical properties of Al-substituted alpha-Ni(OH)(2) samples containing different amounts of Mg2+ or Co2+ were examined by X-ray diffraction, AES and ICP. The effects of Mg2+ and Co2+ on the electrochemical performance of Al-substituted alpha-Ni(OH)(2) such as charge-discharge and diffusion coefficient of the proton (DH+) measured by current pulse relaxation and cycle life were investigated. The results show that the addition of Mg2+ increases the crystal cell parameters and the charge and discharge potentials and decreases the electrochemical polarization. A higher charge efficiency and cycle life are obtained by the addition of Co2+. The addition of both Mg2+ and Co2+ improves DH+ and the stability in alkaline solution at high temperature. The DH+ and R-t of alpha-Ni(OH)(2) electrode reach their maximum and minimum values at about 50% depth of discharge (DOD) and 75% DOD, respectively. (C) 2003 The Electrochemical Society. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35798]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | H. Chen,J. M. Wang,T. Pan,et al. Physicochemical properties and electrochemical performance of Al-substituted alpha-Ni-(OH)(2) with additives for Ni-metal hydride batteries[J]. Journal of the Electrochemical Society,2003,150(11):A1399-A1404. |
| APA | H. Chen,J. M. Wang,T. Pan,Y. L. Zhao,J. Q. Zhang,&C. N. Cao.(2003).Physicochemical properties and electrochemical performance of Al-substituted alpha-Ni-(OH)(2) with additives for Ni-metal hydride batteries.Journal of the Electrochemical Society,150(11),A1399-A1404. |
| MLA | H. Chen,et al."Physicochemical properties and electrochemical performance of Al-substituted alpha-Ni-(OH)(2) with additives for Ni-metal hydride batteries".Journal of the Electrochemical Society 150.11(2003):A1399-A1404. |
入库方式： OAI收割
来源：金属研究所
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