Analysis of ground-state zero-field splitting for Mn2+ in hexagonal ZnS : Mn2+
文献类型：期刊论文
| 作者 | D. Die ; X. Y. Kuang ; W. Lu |
| 刊名 | Journal of Physics and Chemistry of Solids
 |
| 出版日期 | 2003 |
| 卷号 | 64期号:11页码:2121-2123 |
| 关键词 | electron paramagnetic resonance site symmetry ion zns spectra sulfide |
| ISSN号 | 0022-3697 |
| 中文摘要 | The ground state splitting of d(5) configuration ion Mn2+ in ZnS:Mn2+ has been studied by diagonalizing the energy matrices for electron-electron repulsion, spin-orbit coupling and trigonal ligand field interactions. It is shown that in order to give a unified explanation for the EPR parameters a, D and (a - F) for Mn2+ in ZnS:Mn2+, a positive Dq has to be employed. This means that in tetrahedral ZnS the sulfur ion has a positive effective charge. This unusual result supports the Pauling's speculation that the sulfur ion in ZnS may be looked upon as an electron donor that forms a quadricovalent argon state of S2+ with sp(3) hybrid configuration. (C) 2003 Elsevier Ltd. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/35809]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | D. Die,X. Y. Kuang,W. Lu. Analysis of ground-state zero-field splitting for Mn2+ in hexagonal ZnS : Mn2+[J]. Journal of Physics and Chemistry of Solids,2003,64(11):2121-2123. |
| APA | D. Die,X. Y. Kuang,&W. Lu.(2003).Analysis of ground-state zero-field splitting for Mn2+ in hexagonal ZnS : Mn2+.Journal of Physics and Chemistry of Solids,64(11),2121-2123. |
| MLA | D. Die,et al."Analysis of ground-state zero-field splitting for Mn2+ in hexagonal ZnS : Mn2+".Journal of Physics and Chemistry of Solids 64.11(2003):2121-2123. |
入库方式： OAI收割
来源：金属研究所
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