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The internal oxidation of ternary alloys I: The single oxidation of the most-reactive component under low oxidant pressures

文献类型:期刊论文

作者F. Gesmundo ; Y. Niu
刊名Oxidation of Metals
出版日期2003
卷号60期号:5-6页码:347-370
关键词ternary alloys internal oxidation low oxidant pressures oxygen solid-solutions heat-resistant steels solute atoms activity-coefficient dilute solutions binary-alloys liquid alloys fe-ni diffusion thermodynamics
ISSN号0030-770X
中文摘要The internal oxidation of the most-reactive component C of ternary A-B-C alloys by a single oxidant is examined assuming a gas-phase oxidant pressure below the stability of the oxides of the other two components. The precipitation of the most-stable oxide leaves behind a matrix composed of a binary alloy of the two less-reactive components, whose composition affects the solubility and diffusivity of the oxidant within the region of internal oxidation, with an effect on the reaction kinetics. Approximate relations between these properties are proposed and used to predict the kinetics of internal oxidation of C under the assumption of parabolic rate law. The results obtained for the ternary alloys are compared with the behavior of binary A-C and B-C alloys with the same C content. A new important factor in establishing the difference between the internal oxidation in ternary A-B-C alloys and in binary A-C and B-C alloys under a fixed gas-phase oxygen pressure and C content is the ratio between the concentrations of A and B in the bulk ternary alloy.
原文出处://WOS:000186411500001
公开日期2012-04-14
源URL[http://ir.imr.ac.cn/handle/321006/35837]  
专题金属研究所_中国科学院金属研究所
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GB/T 7714
F. Gesmundo,Y. Niu. The internal oxidation of ternary alloys I: The single oxidation of the most-reactive component under low oxidant pressures[J]. Oxidation of Metals,2003,60(5-6):347-370.
APA F. Gesmundo,&Y. Niu.(2003).The internal oxidation of ternary alloys I: The single oxidation of the most-reactive component under low oxidant pressures.Oxidation of Metals,60(5-6),347-370.
MLA F. Gesmundo,et al."The internal oxidation of ternary alloys I: The single oxidation of the most-reactive component under low oxidant pressures".Oxidation of Metals 60.5-6(2003):347-370.

入库方式: OAI收割

来源:金属研究所

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