The ternary system Sm2O3-SrO-CuO: compounds and phase relations
文献类型:期刊论文
作者 | C. Q. Han ; X. L. Chen ; J. K. Liang ; Q. L. Liu ; G. H. Rao |
刊名 | Journal of Alloys and Compounds
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出版日期 | 2001 |
卷号 | 314期号:1-2页码:301-304 |
关键词 | oxide materials rare earth compounds crystal structure phase diagram cu-o system crystal-structure superconductivity 950-degrees-c compatibilities diagram diffraction property |
ISSN号 | 0925-8388 |
中文摘要 | The subsolidus phase relations of the Sm2O3-SrO-CuO ternary system have been investigated by X-ray powder diffraction. All samples were synthesized in air at 950-1000 degreesC. The system can be divided into ten three-phase regions and two solid solutions. In this system, there exist one binary solid solution Sr14-xSmxCu24Oy, one ternary solid solution Sm1+xSr2-xCu2Oy and one ternary compound SmSr3Cu2Oy. The solid solution Sr14-xSmxCu24Oy. (0 less than or equal tox less than or equal to6.5) crystallizes in an orthorhombic unit cell with space group Fmmm and lattice constants of a = 3.950(1)-3.975(1) A, b = 11.475(1)-11.311(3) Angstrom and c = 13.401(2)-12.858(4) Angstrom. The solid solution Sm1+xSr2-xCu2Oy (0 less than or equal tox less than or equal to0.25) belongs to an orthorhombic system with space group Immm, cell parameters a = 3.772(1)-3.774(3) A, b = 11.606(2)-11.226(6) Angstrom and c = 20.053(3)-20.086(3) Angstrom. The ternary compound SmSr3Cu2Oy crystallizes in an orthorhombic unit cell with space group Immm and lattice constants of a = 3.7123(4) Angstrom, b=3.7875(3) Angstrom and c = 12.6395(9) Angstrom. (C) 2001 Elsevier Science B.V. All sights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/36659] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | C. Q. Han,X. L. Chen,J. K. Liang,et al. The ternary system Sm2O3-SrO-CuO: compounds and phase relations[J]. Journal of Alloys and Compounds,2001,314(1-2):301-304. |
APA | C. Q. Han,X. L. Chen,J. K. Liang,Q. L. Liu,&G. H. Rao.(2001).The ternary system Sm2O3-SrO-CuO: compounds and phase relations.Journal of Alloys and Compounds,314(1-2),301-304. |
MLA | C. Q. Han,et al."The ternary system Sm2O3-SrO-CuO: compounds and phase relations".Journal of Alloys and Compounds 314.1-2(2001):301-304. |
入库方式: OAI收割
来源:金属研究所
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