The ternary system Eu2O3-SrO-CuO: Compounds and phase relations
文献类型：期刊论文
| 作者 | C. Q. Han ; X. L. Chen ; J. K. Liang ; Q. L. Liu ; G. H. Rao |
| 刊名 | Journal of Solid State Chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 156期号:1页码:247-250 |
| 关键词 | Eu2O3-SrO-CuO crystal structure phase diagram cu-o system crystal-structure superconductivity 950-degrees-c compatibilities diagram property |
| ISSN号 | 0022-4596 |
| 中文摘要 | The subsolidus phase relations of the Eu2O3-SrO-CuO ternary system have been investigated by X-ray powder diffraction, All samples were synthesized in air at 950-1000 degreesC, The system can be divided into nine three-phase regions and four two-phase regions. In this system, there ex;ist two solid solutions, Sr14-xEuxCu24Oy and Eu1+xSr2-xCu2Oy, and one ternary compound, Eu0.8Sr1.2CuO3.4. The solid solution Sr14-xEuxCu24Oy (9 less than or equal to x less than or equal to 6) crystallizes in an orthorhombic unit cell with space group Fmmm and lattice constants of a = 3.950-3.981 Angstrom, b = 11.475-11.298 Angstrom, and c = 13.401-12.827 Angstrom, The solid solution Eu1+xSr2-xCu2Oy. (0 less than or equal to x less than or equal to 0.4) belongs to an orthorhombic system with space group Immm and cell parameters a = 3.761-3.775 Angstrom, b = 11.385-11.252 Angstrom, and c = 20.019- 20.069 Angstrom. The ternary compound Eu0.8Sr1.2CuO3.4 crystallizes in an orthorhombic unit cell with space group Immm and lattice constants of a = 3.713 Angstrom, b = 3.787 Angstrom, and c = 12.636 Angstrom. A comparison of the Eu system with reported systems of La, Nd, Ho, and Y indicate that the phase diagrams become complicated with an increase in the lanthanide ion size. (C) 2001 Academic Press. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/36660]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | C. Q. Han,X. L. Chen,J. K. Liang,et al. The ternary system Eu2O3-SrO-CuO: Compounds and phase relations[J]. Journal of Solid State Chemistry,2001,156(1):247-250. |
| APA | C. Q. Han,X. L. Chen,J. K. Liang,Q. L. Liu,&G. H. Rao.(2001).The ternary system Eu2O3-SrO-CuO: Compounds and phase relations.Journal of Solid State Chemistry,156(1),247-250. |
| MLA | C. Q. Han,et al."The ternary system Eu2O3-SrO-CuO: Compounds and phase relations".Journal of Solid State Chemistry 156.1(2001):247-250. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。