中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Spin-lattice coupling coefficient G(44) of KMgF3 : Mn2+ calculated from two cases

文献类型:期刊论文

作者S. Y. Wu ; W. C. Zheng
刊名Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
出版日期2001
卷号56期号:3-4页码:253-256
关键词spin-lattice coupling coefficient crystal-field theory electron paramagnetic resonance Mn2+ (EPR) KMgF3 superposition model s-6-state ions spectrum symmetry crystal centers
ISSN号0932-0784
中文摘要The high (fourth) order perturbation formulas based on the dominant spin-orbit coupling mechanism for the zero-field splittings D-tri of a S-6-state ion in trigonal symmetry and E-rho in rhombic symmetry are derived from the strong field scheme. Two analytic expressions of the spin-lattice coupling coefficient G(44) Obtained from the formulas of D-tri and E-rho are established by using a simple and uniform method. Based on the two expressions, the coefficients G(44) for KMgF3:Mn2+ are calculated in two cases. The results show that the lowest (third) order perturbation formulas of D-tri((3)) and E-rho((3)) are too simple and too approximate to give reasonable and consistent values of G44, whereas when the fourth-order perturbation terms D-tri((4)) and E-rho((4)) are considered, the calculated values of G(44) (= G(44)((3)) + G(44)((4))) in both cases are not only close to each other, but also in agreement with the observed value. So, the fourth-order perturbation terms cannot be neglected.
原文出处://WOS:000168723700004
公开日期2012-04-14
源URL[http://ir.imr.ac.cn/handle/321006/36844]  
专题金属研究所_中国科学院金属研究所
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S. Y. Wu,W. C. Zheng. Spin-lattice coupling coefficient G(44) of KMgF3 : Mn2+ calculated from two cases[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2001,56(3-4):253-256.
APA S. Y. Wu,&W. C. Zheng.(2001).Spin-lattice coupling coefficient G(44) of KMgF3 : Mn2+ calculated from two cases.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,56(3-4),253-256.
MLA S. Y. Wu,et al."Spin-lattice coupling coefficient G(44) of KMgF3 : Mn2+ calculated from two cases".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 56.3-4(2001):253-256.

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来源:金属研究所

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