Studies of the EPR parameters for two Gd3+ centers in cubic and tetragonal phases of CsSrCl3 crystals
文献类型:期刊论文
作者 | W. C. Zheng |
刊名 | Physica B-Condensed Matter
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出版日期 | 2000 |
卷号 | 291期号:3-4页码:266-269 |
关键词 | structural phase transition electron paramagnetic resonance superposition model Gd3+ CsSrCl3 perovskite fluorides superposition model transition gd-3+ state splittings rbcaf3 rbcdf3 ion |
ISSN号 | 0921-4526 |
中文摘要 | The zero-field splittings b(2)(m) for the cubic and tetragonal Gd3+ centers in cubic and tetragonal phases of CsSrCl3 crystals are studied from the superposition model. Based on the studies, the superposition model parameters t(2) and (b) over bar(2) for (GdCl6)(3-) groups, the displacement Delta R of the intervening Cl- ion towards the Gd3+ ion in the tetragonal Gd3+ center in cubic phase, the rotational order parameters phi(a) ( = phi, phi is the order parameter in cubic center) and phi(b) ( = 0.67 phi) in tetragonal centers for the rotational axis parallel with and perpendicular to the compensation axis at the cubic to tetragonal phase transition are obtained. The values of these parameters are discussed. (C) 2000 Elsevier Science B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/37279] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng. Studies of the EPR parameters for two Gd3+ centers in cubic and tetragonal phases of CsSrCl3 crystals[J]. Physica B-Condensed Matter,2000,291(3-4):266-269. |
APA | W. C. Zheng.(2000).Studies of the EPR parameters for two Gd3+ centers in cubic and tetragonal phases of CsSrCl3 crystals.Physica B-Condensed Matter,291(3-4),266-269. |
MLA | W. C. Zheng."Studies of the EPR parameters for two Gd3+ centers in cubic and tetragonal phases of CsSrCl3 crystals".Physica B-Condensed Matter 291.3-4(2000):266-269. |
入库方式: OAI收割
来源:金属研究所
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