Studies of the local phase-transition behaviour for Ni+-II centers in RbCaF3 crystal from EPR data
文献类型:期刊论文
作者 | W. C. Zheng ; S. Y. Wu |
刊名 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
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出版日期 | 2000 |
卷号 | 55期号:11-12页码:915-917 |
关键词 | local phase transition behaviour E. P. R. crystal-field theory Ni+ ion RbCaF3 temperature-dependence ligand distances |
ISSN号 | 0932-0784 |
中文摘要 | By fitting the calculated EPR g(i)(i = x, y, z) factors to the observed values, the local release factor k(l) which is introduced to characterize the release (or elongation) effect of impurity-ligand bonds along the rotational axis in the cubic-to-tetragonal phase transition of ABX(3) perovskites, is obtained for the Ni+-II center in RbCaF3 crystal. The result shows that, similar to the local rotational angle (or order parameter) phi, the local release factor is unlike that of the host crystal. It suggests that in the doped crystal the impurity can affect the local phase transition behaviour in the vicinity of impurity ions. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/37282] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,S. Y. Wu. Studies of the local phase-transition behaviour for Ni+-II centers in RbCaF3 crystal from EPR data[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2000,55(11-12):915-917. |
APA | W. C. Zheng,&S. Y. Wu.(2000).Studies of the local phase-transition behaviour for Ni+-II centers in RbCaF3 crystal from EPR data.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,55(11-12),915-917. |
MLA | W. C. Zheng,et al."Studies of the local phase-transition behaviour for Ni+-II centers in RbCaF3 crystal from EPR data".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 55.11-12(2000):915-917. |
入库方式: OAI收割
来源:金属研究所
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