Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys
文献类型:期刊论文
作者 | D. M. Chen ; L. Chen ; K. Yang ; M. Tong ; R. B. Long ; W. S. Sun ; Y. Y. Li |
刊名 | Journal of Alloys and Compounds
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出版日期 | 1999 |
卷号 | 293页码:724-727 |
关键词 | metal-hydride electrodes AB rare earth intermetallic compounds type hydrogen storage alloys melt spinning hydrogen storage alloys metal hydride battery low-cost surface |
ISSN号 | 0925-8388 |
中文摘要 | Sn-substituted, LaNi5-based rapidly solidified alloys with low Co content, La(1-x)A(x)Ni(4.25)Co(0.5)Sn(0.25)(A=La, Nd, Ce,and x=0.2),were prepared by melt-spinning. The microstructure of the as-spun alloys was observed with SERI and the element distribution of the as-spun and annealed alloys was analyzed by EDX. It is found that the as-spun alloys had fine grains. However, there was Sn segregation in the grain boundaries of the as-spun alloys. XRD patterns show that for the as-spun alloys the lattice strain could be alleviated through vacuum annealing. The electrochemical performance of the as-spun and heat-treated alloys was investigated. It is found that the Ce-containing as-spun alloy had a cycle Life more than 300 cycles. After heat-treatment, the electrochemical performance of the Ce-free alloys could be further improved, which is attributed to the alleviation of the lattice strain and the change of Sn distribution. (C) 1999 Elsevier Science S.A. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/37313] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | D. M. Chen,L. Chen,K. Yang,et al. Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys[J]. Journal of Alloys and Compounds,1999,293:724-727. |
APA | D. M. Chen.,L. Chen.,K. Yang.,M. Tong.,R. B. Long.,...&Y. Y. Li.(1999).Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys.Journal of Alloys and Compounds,293,724-727. |
MLA | D. M. Chen,et al."Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys".Journal of Alloys and Compounds 293(1999):724-727. |
入库方式: OAI收割
来源:金属研究所
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