中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys

文献类型:期刊论文

作者D. M. Chen ; L. Chen ; K. Yang ; M. Tong ; R. B. Long ; W. S. Sun ; Y. Y. Li
刊名Journal of Alloys and Compounds
出版日期1999
卷号293页码:724-727
关键词metal-hydride electrodes AB rare earth intermetallic compounds type hydrogen storage alloys melt spinning hydrogen storage alloys metal hydride battery low-cost surface
ISSN号0925-8388
中文摘要Sn-substituted, LaNi5-based rapidly solidified alloys with low Co content, La(1-x)A(x)Ni(4.25)Co(0.5)Sn(0.25)(A=La, Nd, Ce,and x=0.2),were prepared by melt-spinning. The microstructure of the as-spun alloys was observed with SERI and the element distribution of the as-spun and annealed alloys was analyzed by EDX. It is found that the as-spun alloys had fine grains. However, there was Sn segregation in the grain boundaries of the as-spun alloys. XRD patterns show that for the as-spun alloys the lattice strain could be alleviated through vacuum annealing. The electrochemical performance of the as-spun and heat-treated alloys was investigated. It is found that the Ce-containing as-spun alloy had a cycle Life more than 300 cycles. After heat-treatment, the electrochemical performance of the Ce-free alloys could be further improved, which is attributed to the alleviation of the lattice strain and the change of Sn distribution. (C) 1999 Elsevier Science S.A. All rights reserved.
原文出处://WOS:000084065500136
公开日期2012-04-14
源URL[http://ir.imr.ac.cn/handle/321006/37313]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
D. M. Chen,L. Chen,K. Yang,et al. Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys[J]. Journal of Alloys and Compounds,1999,293:724-727.
APA D. M. Chen.,L. Chen.,K. Yang.,M. Tong.,R. B. Long.,...&Y. Y. Li.(1999).Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys.Journal of Alloys and Compounds,293,724-727.
MLA D. M. Chen,et al."Electrochemical performance of Sn-substituted, LaNi5-based rapidly solidified alloys".Journal of Alloys and Compounds 293(1999):724-727.

入库方式: OAI收割

来源:金属研究所

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