Study on copolymerization of quaternary alkyl salts of dimethylaminoethyl methacrylate with styrene
文献类型：期刊论文
| 作者 | E. F. Chen ; C. L. Zhao ; Y. J. Cheng ; B. L. Zhou |
| 刊名 | Acta Polymerica Sinica
 |
| 出版日期 | 1999 |
| 期号 | 5页码:588-595 |
| 关键词 | amphiphilic copolymer quaternary alkyl salt monomer dimethylaminoethyl methacrylate styrene solution polymerization reactivity ratios |
| ISSN号 | 1000-3304 |
| 中文摘要 | A new kind of amphiphilic random copolymers has been synthesized by radical copolymerization of quaternary alkyl salts of dimethylaminoethyl methacrylate (QASDMAEMA) with styrene (St) in solution, in which the salts are butyl-bromide salt (MABB) and ethyl-bromide salt (MAEB), respectively. Various experimental parameters of the copolymerization and the solubility of copolymers were studied in detail. The structure of copolymers was determined by the spectra of IR, H-1-NMR and C-13-NMR, which are perfectly consistent with the expected macro-molecular structure of the random copolymer with both hydrophobic and hydrophilic chain units. Finally, monomer reactivity ratios of MABB/St and MAEB/St were obtained, r(MABB) = 0.44, r(St) = 0.15; r(MAEB) = 0.66, r(St) = 0.36, using YBR method. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/37314]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | E. F. Chen,C. L. Zhao,Y. J. Cheng,et al. Study on copolymerization of quaternary alkyl salts of dimethylaminoethyl methacrylate with styrene[J]. Acta Polymerica Sinica,1999(5):588-595. |
| APA | E. F. Chen,C. L. Zhao,Y. J. Cheng,&B. L. Zhou.(1999).Study on copolymerization of quaternary alkyl salts of dimethylaminoethyl methacrylate with styrene.Acta Polymerica Sinica(5),588-595. |
| MLA | E. F. Chen,et al."Study on copolymerization of quaternary alkyl salts of dimethylaminoethyl methacrylate with styrene".Acta Polymerica Sinica .5(1999):588-595. |
入库方式： OAI收割
来源：金属研究所
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