Studies on DC conductivity and magnetic susceptibility of polyaniline doped with different acids
文献类型:期刊论文
作者 | A. M. Elamin ; K. L. Yao |
刊名 | Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers
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出版日期 | 1999 |
卷号 | 38期号:8页码:4809-4811 |
关键词 | polyaniline dc conductivity magnetic susceptibility quasi-one-dimensional variable-range hopping electron localization charge-transport emeraldine |
ISSN号 | 0021-4922 |
中文摘要 | We report a comparative study among four kinds of polyaniline (PANI) synthesized with four different kinds of acids, under the same conditions for synthesis; PANI-HCl, PANI-H2SO4, PANI-H3PO4 and PANI-C4H6O6. We measured the temperature dependence of the dc conductivity sigma(dc)(T) and the magnetic susceptibility chi(tot)(T) The room-temperature conductivity of HCl and H2SO4-polyaniline was 5-8 times higher than that of H3PO4 and C4H6O6-polyaniline, in which the values of 18.1, 16.8, 3.8 and 1.85 S/cm were found, respectively. The best fit for our de conductivity data was obtained using the quasi-one-dimensional variable-range hopping (QID VRH) model between nearest neighbors. Polyaniline reported in this paper leads to a high magnetic susceptibility chi(tot) (at T = 295 K) of 10(-4) emu/mol.2rings. This is one or two orders of magnitude higher than those reported earlier for polyaniline. Data on sigma(dc)(T) and chi(tot)(T) are also discussed. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/37351] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | A. M. Elamin,K. L. Yao. Studies on DC conductivity and magnetic susceptibility of polyaniline doped with different acids[J]. Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers,1999,38(8):4809-4811. |
APA | A. M. Elamin,&K. L. Yao.(1999).Studies on DC conductivity and magnetic susceptibility of polyaniline doped with different acids.Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers,38(8),4809-4811. |
MLA | A. M. Elamin,et al."Studies on DC conductivity and magnetic susceptibility of polyaniline doped with different acids".Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers 38.8(1999):4809-4811. |
入库方式: OAI收割
来源:金属研究所
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