Crystal structure and magnetic properties of the intermetallic compounds La2Co17-xMx (M = Nb, Mo, Mn)
文献类型:期刊论文
作者 | Q. L. Liu ; J. K. Liang ; F. Huang ; Y. Chen ; G. H. Rao ; X. L. Chen ; B. G. Shen |
刊名 | Journal of Physics-Condensed Matter
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出版日期 | 1999 |
卷号 | 11期号:48页码:9797-9805 |
关键词 | uniaxial magnetocrystalline anisotropy permanent-magnets nd fe phase pr gd |
ISSN号 | 0953-8984 |
中文摘要 | Novel ternary intermetallic compounds La2Co17-xMx (M = Nb, Mo, Mn) with Th2Zn17-type structure were synthesized and their homogeneous ranges were determined: 0.3 less than or equal to x less than or equal to 0.6 for Nb, 0.6 less than or equal to x less than or equal to 1.2 for Mo and 1.0 less than or equal to x less than or equal to 4.0 for Mn. The lattice parameters and the unit-cell volume increase with increasing x in all of the systems. The preferential occupancy of 6c crystallographic positions (dumb-bell sites) and the stabilization of these compounds by M atoms are attributed to the atomic-size and enthalpy effects. These compounds exhibit favourable uniaxial anisotropy with M content x greater than or equal to 0.5. The Curie temperature decreases monotonically with increasing x for all of the systems. The saturation moment , decreases rapidly with increasing x for M = Mo and Nb. In the La2Co17-xMnx system, mu(s) increases slightly with x for x less than or equal to 2.5 and then decreases for x > 2.5. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/37427] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Q. L. Liu,J. K. Liang,F. Huang,et al. Crystal structure and magnetic properties of the intermetallic compounds La2Co17-xMx (M = Nb, Mo, Mn)[J]. Journal of Physics-Condensed Matter,1999,11(48):9797-9805. |
APA | Q. L. Liu.,J. K. Liang.,F. Huang.,Y. Chen.,G. H. Rao.,...&B. G. Shen.(1999).Crystal structure and magnetic properties of the intermetallic compounds La2Co17-xMx (M = Nb, Mo, Mn).Journal of Physics-Condensed Matter,11(48),9797-9805. |
MLA | Q. L. Liu,et al."Crystal structure and magnetic properties of the intermetallic compounds La2Co17-xMx (M = Nb, Mo, Mn)".Journal of Physics-Condensed Matter 11.48(1999):9797-9805. |
入库方式: OAI收割
来源:金属研究所
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