Raman scattering and x-ray diffraction study of a phase transition in (ND4)(2)TeBr6
文献类型:期刊论文
作者 | J. R. Shi ; Y. C. Xu ; B. Arnscheidt ; J. Pelzl ; X. Wu |
刊名 | Journal of Raman Spectroscopy
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出版日期 | 1996 |
卷号 | 27期号:9页码:691-694 |
关键词 | ammonium hexachlorotellurate thermodynamic properties deuterated (nh4)2tecl6 heat-capacity temperatures |
ISSN号 | 0377-0486 |
中文摘要 | Raman spectra of (ND4)(2)TeBr6 were recorded in the temperature range 5-300 K, A continuous minimum of the Raman shift and a continuous maximum of the linewidth of the A(1g) mode of the TeBr62- octahedron were observed at T-c = 68 K. Also, the T-2g mode of the TeBr62- octahedron continuously split into two lines below T-c. X-ray diffraction measurements at 10 K indicate that the low-temperature phase has a primitive tetragonal structure, and an antiferro-rotation of the TeBr62- octahedra is associated with the transition. This behaviour indicates a displacive phase transition at T-c. |
原文出处 | |
公开日期 | 2012-04-14 |
源URL | [http://ir.imr.ac.cn/handle/321006/38394] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. R. Shi,Y. C. Xu,B. Arnscheidt,et al. Raman scattering and x-ray diffraction study of a phase transition in (ND4)(2)TeBr6[J]. Journal of Raman Spectroscopy,1996,27(9):691-694. |
APA | J. R. Shi,Y. C. Xu,B. Arnscheidt,J. Pelzl,&X. Wu.(1996).Raman scattering and x-ray diffraction study of a phase transition in (ND4)(2)TeBr6.Journal of Raman Spectroscopy,27(9),691-694. |
MLA | J. R. Shi,et al."Raman scattering and x-ray diffraction study of a phase transition in (ND4)(2)TeBr6".Journal of Raman Spectroscopy 27.9(1996):691-694. |
入库方式: OAI收割
来源:金属研究所
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