THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL
文献类型：期刊论文
| 作者 | Z. Wenchen |
| 刊名 | Journal of Physics and Chemistry of Solids
 |
| 出版日期 | 1993 |
| 卷号 | 54期号:11页码:1587-1592 |
| 关键词 | electron paramagnetic resonance superposition model local lattice relaxation mn2+ ion na2zncl43h2o s-6-state ions parameters symmetry spectra linbo3 site |
| ISSN号 | 0022-3697 |
| 中文摘要 | In order to overcome the difficulties in explaining the zero-field splitting and its stress (along the C3 axis) and hydrostatic pressure dependence for Na2ZnCl4.3H2O:Mn2+ crystal, which arise in previous work, we assume, in this paper, that the Mn2+ ion does not occupy the exact substitutional position of Zn2+ ion in Na2ZnCl4-3H2O, but is displaced about 0.3 angstrom on the C3 axis. Based on this, the zero-field splitting and its stress and pressure dependence have been calculated using the superposition model (and also the spin-orbit coupling mechanism), the results show reasonable agreement with the experimental findings. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/39149]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Z. Wenchen. THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL[J]. Journal of Physics and Chemistry of Solids,1993,54(11):1587-1592. |
| APA | Z. Wenchen.(1993).THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL.Journal of Physics and Chemistry of Solids,54(11),1587-1592. |
| MLA | Z. Wenchen."THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL".Journal of Physics and Chemistry of Solids 54.11(1993):1587-1592. |
入库方式： OAI收割
来源：金属研究所
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