A STUDY OF ZERO-FIELD SPLITTING IN CS3ZNCL5MN2+
文献类型：期刊论文
| 作者 | W. C. Zheng |
| 刊名 | Journal of Physics and Chemistry of Solids
 |
| 出版日期 | 1992 |
| 卷号 | 53期号:8页码:1017-1019 |
| 关键词 | electron paramagnetic resonance zero-field splitting superposition model crystal field theory cs3zncl5 s-6-state ions parameters spectra ligand |
| ISSN号 | 0022-3697 |
| 中文摘要 | In this paper. the intrinsic zero-field splitting parameter b2BAR of the superposition model for a crystal of Cs3ZnCl5:Mn2+ has been calculated from the spin-orbit coupling mechanism, relativistic mechanism, and covalency and overlap mechanism. The result is close to that obtained from the observed zero-field splitting and X-ray diffraction data for Cs3ZnCl5 and the small discrepancy between calculation and experiment is discussed. It appears that there are several mechanisms which contribute to the zero-field splitting of Mn2+ in Cs3ZnCl5, and, hence, the intrinsic parameter b2BAR involves cancellation effects among these competing mechanisms. |
| 原文出处 | |
| 公开日期 | 2012-04-14 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/39362]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. C. Zheng. A STUDY OF ZERO-FIELD SPLITTING IN CS3ZNCL5MN2+[J]. Journal of Physics and Chemistry of Solids,1992,53(8):1017-1019. |
| APA | W. C. Zheng.(1992).A STUDY OF ZERO-FIELD SPLITTING IN CS3ZNCL5MN2+.Journal of Physics and Chemistry of Solids,53(8),1017-1019. |
| MLA | W. C. Zheng."A STUDY OF ZERO-FIELD SPLITTING IN CS3ZNCL5MN2+".Journal of Physics and Chemistry of Solids 53.8(1992):1017-1019. |
入库方式： OAI收割
来源：金属研究所
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