中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
SPIN-LATTICE COUPLING-COEFFICIENTS G(11) AND G(44) FOR 3D(5) IONS IN 12-FOLD CUBIC COORDINATION

文献类型:期刊论文

作者W. C. Zheng
刊名Physica B-Condensed Matter
出版日期1992
卷号179期号:1页码:35-42
关键词s-6-state ions symmetry formulas
ISSN号0921-4526
中文摘要Similar to the cases of 3d(n) ions in 4-fold (or 8-fold) and 6-fold cubic coordinations, a simple and uniform method that calculates the spin-lattice coupling coefficients G11 and G44 for those ions in the more complex 12-fold cubic coordination from the derivatives of zero-field splittings in low symmetries with respect to the distinct structural parameters has been established. Through this method, the analytic expressions of G11 and G44 for 3d5 ions in this cubic coordination based on various mechanisms and models have been given. The results are rather different from those in 4-fold (or 8-fold) and 6-fold cubic coordinations. As an example, the coefficients G11 and G44 for Fe3+ in K+ site ( 12-fold cubic coordination) as well as Ta5+ site (6-fold cubic coordination) of KTaO3 crystal are studied from the important spin-orbit coupling mechanism. When we compare these results with the experimental findings, it appears that the Fe3+ ion is in a Ta5+ site, and not in a K+ site as shown by some researchers.
原文出处://WOS:A1992HV63300005
公开日期2012-04-14
源URL[http://ir.imr.ac.cn/handle/321006/39365]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
W. C. Zheng. SPIN-LATTICE COUPLING-COEFFICIENTS G(11) AND G(44) FOR 3D(5) IONS IN 12-FOLD CUBIC COORDINATION[J]. Physica B-Condensed Matter,1992,179(1):35-42.
APA W. C. Zheng.(1992).SPIN-LATTICE COUPLING-COEFFICIENTS G(11) AND G(44) FOR 3D(5) IONS IN 12-FOLD CUBIC COORDINATION.Physica B-Condensed Matter,179(1),35-42.
MLA W. C. Zheng."SPIN-LATTICE COUPLING-COEFFICIENTS G(11) AND G(44) FOR 3D(5) IONS IN 12-FOLD CUBIC COORDINATION".Physica B-Condensed Matter 179.1(1992):35-42.

入库方式: OAI收割

来源:金属研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。