Formation and characterization of PrGa0.9Mg0.1O3 synthesized by a citric acid method
文献类型:期刊论文
作者 | Z. G. Liu ; Z. Lu ; X. Q. Huang ; D. P. Xu ; Y. Sui ; J. P. Miao ; T. M. He ; D. W. Dong ; R. B. Zhu ; Y. Q. Liu ; W. H. Su |
刊名 | Journal of Alloys and Compounds
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出版日期 | 2005 |
卷号 | 393期号:1-2页码:274-278 |
关键词 | oxides chemical synthesis thermogravimetric analysis electron microscopy perovskite-type oxide mg-doped lagao3 conductivity electrolyte |
ISSN号 | 0925-8388 |
中文摘要 | PrGa0.9Mg0.1O3 was synthesized by using a citric acid method. Compared with the sample prepared by the solid state technique, the sample synthesized by the citric acid method crystallized at a lower temperature. X-ray diffraction data indicated that a pure orthorhombic phase was formed at 1300 degrees C. PrGa0.9Mg0.1O3 showed a conductivity of 0.076 S/cm at 800 degrees C and an activation energy of 32.98 kJ/mol. Its average thermal expansion coefficient from 600 to 1000 degrees C was 11.9 x 10(-6) K-1, which well matches with the NiO/YSZ anode and doped LaMnO3 cathode. A power density of 55 mW/cm(2) and a short circuit current density of 200 mA/cm(2) were obtained at 900 degrees C in a single fuel cell experiment by using PrGa0.9Mg0.1O3 as an electrolyte. This could be attributed to the existence of hole conduction in the sample. (c) 2004 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-05-17 |
源URL | [http://ir.imr.ac.cn/handle/321006/40015] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Z. G. Liu,Z. Lu,X. Q. Huang,et al. Formation and characterization of PrGa0.9Mg0.1O3 synthesized by a citric acid method[J]. Journal of Alloys and Compounds,2005,393(1-2):274-278. |
APA | Z. G. Liu.,Z. Lu.,X. Q. Huang.,D. P. Xu.,Y. Sui.,...&W. H. Su.(2005).Formation and characterization of PrGa0.9Mg0.1O3 synthesized by a citric acid method.Journal of Alloys and Compounds,393(1-2),274-278. |
MLA | Z. G. Liu,et al."Formation and characterization of PrGa0.9Mg0.1O3 synthesized by a citric acid method".Journal of Alloys and Compounds 393.1-2(2005):274-278. |
入库方式: OAI收割
来源:金属研究所
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