Energy spectrum of YAG : Cr3+ and thermal shifts of its R lines
文献类型：期刊论文
| 作者 | D. P. Ma ; J. R. Chen |
| 刊名 | Communications in Theoretical Physics
 |
| 出版日期 | 2005 |
| 卷号 | 44期号:1页码:165-170 |
| 关键词 | improved ligand-field theory electron-phonon interaction Stokes shift energy spectrum thermal shift g factor yttrium-aluminum-garnet pressure cr3 temperature state ions |
| ISSN号 | 0253-6102 |
| 中文摘要 | Traditional ligand-field theory has to be improved by taking into account both "pure electronic" contribution and electron-phonon interaction one (including lattice-vibrational relaxation energy). By means of improved ligand-field theory, R-1, R-2, R-3', R-2', and R-1' lines, U band, ground-state zero-field-splitting (GSZFS) and ground-state g factors as well as thermal shifts of R-1 line and R-2 line of yAG:Cr3+ have been calculated. The results are in very good agreement with the experimental data. In contrast with ruby, the octahedron of ligand oxygen ions surrounding the central Cr3+ ion in YAG:Cr is compressed along the [111] direction. Thus, for YAG:Cr3+ and ruby, the splitting of t(2)(3) (4)A(2) (or t(2)(3) E-2) has opposite order, and the trigonal-field parameters of the two crystals have opposite signs. In thermal shifts of R-1 and R-2 lines of YAG:Cr3+, the temperature-dependent contributions due to EPI are dominant. |
| 原文出处 | |
| 公开日期 | 2012-05-17 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/40032]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | D. P. Ma,J. R. Chen. Energy spectrum of YAG : Cr3+ and thermal shifts of its R lines[J]. Communications in Theoretical Physics,2005,44(1):165-170. |
| APA | D. P. Ma,&J. R. Chen.(2005).Energy spectrum of YAG : Cr3+ and thermal shifts of its R lines.Communications in Theoretical Physics,44(1),165-170. |
| MLA | D. P. Ma,et al."Energy spectrum of YAG : Cr3+ and thermal shifts of its R lines".Communications in Theoretical Physics 44.1(2005):165-170. |
入库方式： OAI收割
来源：金属研究所
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