中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Pressure-induced shifts of R,R ', and B line-groups and ground-state zero-field-splitting of ruby

文献类型:期刊论文

作者D. P. Ma ; J. R. Chen
刊名Communications in Theoretical Physics
出版日期2005
卷号43期号:5页码:941-947
关键词high-pressure effect electron-phonon interaction R R ' and B line-groups ground-state zero-field-splitting admixture of [t(2)(2)(T-3(1))e(4)T(2)) and [t(2)(3)(2) E) laser crystal calibration spectra
ISSN号0253-6102
中文摘要By means of improved ligand-field theory, the "pure electronic" presure-induced shifts (PSs) and the PSs due to electron-phonon interaction (EPI) of the R-1, R-2, B-1, B-2, B-3, and R-3' lines and the ground-state zero-lield-splitting' of ruby have been uniformly calculated. The calculation results are in very good agreement with all the experimental data. At normal pressure, ruby is a crystal with very strong crystal field. Thus the admixture of vertical bar t(2)(2)(T-3(1))e(4)T(2)> and vertical bar t(2)(32)E > bases in the wavefunction of R-1 level of ruby is small at normal pressure, and it gradually decreases with increasing pressure, which causes the R-1-line PS of ruby to monotonously red shift with approximate linearity. The combined effect of the pure electronic PS of R, line and the PS of R, line due to EPI gives rise to the total PS of R, line. The analyses and comparisons among the features of R-1-line PSs of three laser crystals (ruby, GSGG:Cr3+ and GGG:Cr3+) have been made, and the origin of their difference has been revealed.
原文出处://WOS:000229449000037
公开日期2012-05-17
源URL[http://ir.imr.ac.cn/handle/321006/40033]  
专题金属研究所_中国科学院金属研究所
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D. P. Ma,J. R. Chen. Pressure-induced shifts of R,R ', and B line-groups and ground-state zero-field-splitting of ruby[J]. Communications in Theoretical Physics,2005,43(5):941-947.
APA D. P. Ma,&J. R. Chen.(2005).Pressure-induced shifts of R,R ', and B line-groups and ground-state zero-field-splitting of ruby.Communications in Theoretical Physics,43(5),941-947.
MLA D. P. Ma,et al."Pressure-induced shifts of R,R ', and B line-groups and ground-state zero-field-splitting of ruby".Communications in Theoretical Physics 43.5(2005):941-947.

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来源:金属研究所

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