Synthesis of Graft Copolymers from a Linear Polyolefin Through a Combination of Coordination Polymerization and Atom Transfer Radical Polymerization
文献类型:期刊论文
作者 | Liu XH ; Zheng Y ; Pan L ; Li YG ; Li YS |
刊名 | journal of applied polymer science
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出版日期 | 2010 |
卷号 | 117期号:1页码:450-457 |
关键词 | BLOCK-COPOLYMERS CATALYZED COPOLYMERIZATION FUNCTIONAL POLYOLEFIN METHYL ACRYLATE VINYL-ACETATE POLYETHYLENE ETHYLENE INITIATORS CHLORIDE METHACRYLATES |
ISSN号 | 0021-8995 |
通讯作者 | li ys |
中文摘要 | this article reports on a facile route for the preparation of methyl acrylate and methyl methacrylate graft copolymers via a combination of catalytic olefin copolymerization and atom transfer radical polymerization (atrp). the chemistry first involved a transforming process from ethylene/allylbenzene copolymers to a polyolefin multifunctional macroinitiator with pendant sulfonyl chloride groups. the key to the success of the graft copolymerization was ascribed to a fast exchange rate between the dormant species and active radical species by optimization of the various experimental parameters. polyolefin-g-poly(methyl methacrylate) and polyolefin-g-poly(methyl acrylate) graft copolymers with controlled architecture and various graft lengths were, thus, successfully prepared under dilute atrp conditions. (c) 2010 wiley periodicals, inc. j appl polym sci 117: 450-457, 2010 |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000277523500055 |
公开日期 | 2012-06-06 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43726] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu XH,Zheng Y,Pan L,et al. Synthesis of Graft Copolymers from a Linear Polyolefin Through a Combination of Coordination Polymerization and Atom Transfer Radical Polymerization[J]. journal of applied polymer science,2010,117(1):450-457. |
APA | Liu XH,Zheng Y,Pan L,Li YG,&Li YS.(2010).Synthesis of Graft Copolymers from a Linear Polyolefin Through a Combination of Coordination Polymerization and Atom Transfer Radical Polymerization.journal of applied polymer science,117(1),450-457. |
MLA | Liu XH,et al."Synthesis of Graft Copolymers from a Linear Polyolefin Through a Combination of Coordination Polymerization and Atom Transfer Radical Polymerization".journal of applied polymer science 117.1(2010):450-457. |
入库方式: OAI收割
来源:长春应用化学研究所
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