Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer
文献类型:期刊论文
作者 | Kumar S ; Nigama N ; Ghosh T ; Dutta PK ; Singh SP ; atta PK ; An LJ ; Shi TF |
刊名 | materials chemistry and physics
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出版日期 | 2010 |
卷号 | 120期号:2-3页码:361-370 |
关键词 | 2ND-HARMONIC GENERATION THIN-FILMS POLYMERS CHROMOPHORES DESIGN DYES |
ISSN号 | 0254-0584 |
通讯作者 | dutta pk |
中文摘要 | the efficient procedure for preparation of azo-based chitosan biopolymer using chitosan and 2-(4-dimethylaminophenylazo)benzoic acid (methyl red) in isopropyl alcohol under mild condition has been demonstrated. after the reaction, the product was successively washed with an isopropyl alcohol and water mixture (5:1, v/v) and dried in air. finally, the obtained product was confirmed and characterized by uv-vis, ftir, h-1 nmr spectroscopy and xrd. the thermal, surface morphology and optical properties were evaluated by tga, dsc, sem, afm, photoluminescence (pl) spectroscopy and second harmonic generation (shg) studies. the maximum molar absorption coefficient (epsilon(max)), and correlation coefficient (r) were -0.0112 l mol(-1) cm(-1) and 0.998. absorption of the derivative was high (10(4) cm(-1)) with optical band gap of 2.37 ev. the azo-based chitosan derivative may be considered as a novel optical material from biomedical application point of views. (c) 2009 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000276984600024 |
公开日期 | 2012-06-06 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43758] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Kumar S,Nigama N,Ghosh T,et al. Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer[J]. materials chemistry and physics,2010,120(2-3):361-370. |
APA | Kumar S.,Nigama N.,Ghosh T.,Dutta PK.,Singh SP.,...&Shi TF.(2010).Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer.materials chemistry and physics,120(2-3),361-370. |
MLA | Kumar S,et al."Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer".materials chemistry and physics 120.2-3(2010):361-370. |
入库方式: OAI收割
来源:长春应用化学研究所
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