中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer

文献类型:期刊论文

作者Kumar S ; Nigama N ; Ghosh T ; Dutta PK ; Singh SP ; atta PK ; An LJ ; Shi TF
刊名materials chemistry and physics
出版日期2010
卷号120期号:2-3页码:361-370
关键词2ND-HARMONIC GENERATION THIN-FILMS POLYMERS CHROMOPHORES DESIGN DYES
ISSN号0254-0584
通讯作者dutta pk
中文摘要the efficient procedure for preparation of azo-based chitosan biopolymer using chitosan and 2-(4-dimethylaminophenylazo)benzoic acid (methyl red) in isopropyl alcohol under mild condition has been demonstrated. after the reaction, the product was successively washed with an isopropyl alcohol and water mixture (5:1, v/v) and dried in air. finally, the obtained product was confirmed and characterized by uv-vis, ftir, h-1 nmr spectroscopy and xrd. the thermal, surface morphology and optical properties were evaluated by tga, dsc, sem, afm, photoluminescence (pl) spectroscopy and second harmonic generation (shg) studies. the maximum molar absorption coefficient (epsilon(max)), and correlation coefficient (r) were -0.0112 l mol(-1) cm(-1) and 0.998. absorption of the derivative was high (10(4) cm(-1)) with optical band gap of 2.37 ev. the azo-based chitosan derivative may be considered as a novel optical material from biomedical application point of views. (c) 2009 elsevier b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000276984600024
公开日期2012-06-06
源URL[http://ir.ciac.jl.cn/handle/322003/43758]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Kumar S,Nigama N,Ghosh T,et al. Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer[J]. materials chemistry and physics,2010,120(2-3):361-370.
APA Kumar S.,Nigama N.,Ghosh T.,Dutta PK.,Singh SP.,...&Shi TF.(2010).Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer.materials chemistry and physics,120(2-3),361-370.
MLA Kumar S,et al."Preparation, characterization and optical properties of a novel azo-based chitosan biopolymer".materials chemistry and physics 120.2-3(2010):361-370.

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来源:长春应用化学研究所

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