Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications
文献类型：期刊论文
| 作者 | Wang JH ; Li SH ; Zhang SB |
| 刊名 | macromolecules
 |
| 出版日期 | 2010 |
| 卷号 | 43期号:8页码:3890-3896 |
| 关键词 | ANION-EXCHANGE MEMBRANES POLYMER ELECTROLYTE STATE POLYETHERSULFONE TEMPERATURE COPOLYMERS STABILITY CHLORIDE CATION |
| ISSN号 | 0024-9297 |
| 通讯作者 | zhang sb |
| 中文摘要 | poly(arylene ether sulfone)s were functionalized with quaternary guanidinium groups in order to investigate their properties as novel polymeric hydroxide exchange membrane materials. the quaternized polymers were synthesized via chloromethylation of poly(arylene ether sulfone)s, followed by reactions with pentamethylguanidine. the resulting quaternized polymers psgci-x (where x represents the number of the quaternary guanidinium groups/repeat units) presented an elevated molecular weight and exhibited an outstanding solubility in polar aprotic solvents. consequently flexible and tough membranes of psgci-x with varying ionic content could be prepared by casting from the dmso solution. novel anion exchange membranes, psgoh-x, were obtained by an anion exchange of psgci-x with i m naoh at room temperature. the membranes displayed a high ionic conductivity and an excellent chemical stability. the obtained alkaline anion exchange membranes (a ems) showed conductivities almost above 10(-2) s cm(-1) at room temperature; the hydroxide conductivity of psgoh-1.4 was for instance found to be 6.7 x 10(-2) s cm(-1). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000276811700039 |
| 公开日期 | 2012-06-06 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43778]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang JH,Li SH,Zhang SB. Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications[J]. macromolecules,2010,43(8):3890-3896. |
| APA | Wang JH,Li SH,&Zhang SB.(2010).Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications.macromolecules,43(8),3890-3896. |
| MLA | Wang JH,et al."Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications".macromolecules 43.8(2010):3890-3896. |
入库方式： OAI收割
来源：长春应用化学研究所
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