Crystallization-Induced Phase Segregation Based on Double-Crystalline Blends of Poly(3-hexylthiophene) and Poly(ethylene glycol)s
文献类型：期刊论文
| 作者 | Zhao K ; Ding ZC ; Xue LJ ; Han YC |
| 刊名 | macromolecular rapid communications
 |
| 出版日期 | 2010 |
| 卷号 | 31期号:6页码:532-538 |
| 关键词 | THIN-FILM TRANSISTORS FIELD-EFFECT TRANSISTORS PLASTIC SOLAR-CELLS REGIOREGULAR POLY(3-HEXYLTHIOPHENE) DIBLOCK COPOLYMERS CONJUGATED POLYMER THERMAL-TREATMENT MORPHOLOGY PERFORMANCE SURFACE |
| ISSN号 | 1022-1336 |
| 通讯作者 | han yc |
| 中文摘要 | crystallization-induced vertical stratified structures were constructed based on double-crystalline poly(3-hexylthiophene) (p3ht)/poly(ethylene glycol)s (peg) systems at room temperature, in which the p3ht crystallinity and the mechanism were investigated. vertical stratified microstructures with highly crystalline p3ht network on the surface were formed when depositing from marginal solvents, while lateral phase-separated structures or low p3ht crystallinity were observed for good solvents. the morphological differences came from the solvent effect. in marginal solvents, p-xylene and dichloromethane, p3ht large-scale microcrystallites were generated in solution, which ensured the priority of p3ht crystalline sequence, and phase separation began in the liquid states. when the peg matrix began to crystallize, great energy from which the second phase separation was induced drove p3ht crystallites to the surface, resulting in the formation of vertical stratified microstructures with highly crystalline p3ht network on the surface. the method, crystallization-induced phase segregation of crystalline crystalline blends in marginal solvent, provides a facile way to construct vertically stratified structures, in which p3ht highly crystalline network is favored. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000276666500003 |
| 公开日期 | 2012-06-06 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43779]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao K,Ding ZC,Xue LJ,et al. Crystallization-Induced Phase Segregation Based on Double-Crystalline Blends of Poly(3-hexylthiophene) and Poly(ethylene glycol)s[J]. macromolecular rapid communications,2010,31(6):532-538. |
| APA | Zhao K,Ding ZC,Xue LJ,&Han YC.(2010).Crystallization-Induced Phase Segregation Based on Double-Crystalline Blends of Poly(3-hexylthiophene) and Poly(ethylene glycol)s.macromolecular rapid communications,31(6),532-538. |
| MLA | Zhao K,et al."Crystallization-Induced Phase Segregation Based on Double-Crystalline Blends of Poly(3-hexylthiophene) and Poly(ethylene glycol)s".macromolecular rapid communications 31.6(2010):532-538. |
入库方式： OAI收割
来源：长春应用化学研究所
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