Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent
文献类型:期刊论文
作者 | Li W ; Jiang W |
刊名 | polymer bulletin
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出版日期 | 2010 |
卷号 | 64期号:8页码:805-815 |
关键词 | CONSISTENT-FIELD THEORY ACID) BLOCK-COPOLYMERS ABC TRIBLOCK COPOLYMER DILUTE-SOLUTION AGGREGATE MORPHOLOGIES PHASE-BEHAVIOR SPONTANEOUS CURVATURES POLYMER BLENDS POOR SOLVENTS MICELLES |
ISSN号 | 0170-0839 |
通讯作者 | jiang w |
中文摘要 | three dimensional real-space self-consistent field theory is employed to study the effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent. the phase diagrams in wide ranges of interaction parameters and conformational asymmetry were obtained in present study. the results indicate that the conformational asymmetry is an important factor that determines the self-assembly of amphiphilic diblock copolymer in solution. the self-assembled morphology changes from sphere to rod, then to vesicle with an increase of the degree of conformational asymmetry. we found that the entropic contribution of the core-forming block is the main reason for this transition. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000276440300007 |
公开日期 | 2012-06-06 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43798] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li W,Jiang W. Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent[J]. polymer bulletin,2010,64(8):805-815. |
APA | Li W,&Jiang W.(2010).Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent.polymer bulletin,64(8),805-815. |
MLA | Li W,et al."Effect of conformational asymmetry on the self-assembly of amphiphilic diblock copolymer in selective solvent".polymer bulletin 64.8(2010):805-815. |
入库方式: OAI收割
来源:长春应用化学研究所
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