Ionic-Liquid-Grafted Rigid Poly (p-Phenylene) Microspheres: Efficient Heterogeneous Media for Metal Scavenging and Catalysis
文献类型：期刊论文
| 作者 | Li SH ; Wang JH ; Kou YL ; Zhang SB |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2010 |
| 卷号 | 16期号:6页码:1812-1818 |
| 关键词 | CROSS-COUPLING REACTIONS NUCLEOPHILIC-SUBSTITUTION REACTIONS SPHERICAL POLYELECTROLYTE BRUSHES HECK REACTION PALLADIUM NANOPARTICLES HYDROGENATION CATALYSTS ENCAPSULATED PALLADIUM ORGANIC-SYNTHESIS SUZUKI ARYL |
| ISSN号 | 0947-6539 |
| 通讯作者 | zhang sb |
| 中文摘要 | novel guanidinium ionic liquid-grafted rigid poly(p-phenylene) (ppil) microspheres have been developed for metal scavenging and catalysis. the noble-metal nanoparticles supported on the microspheres surface can be used as efficient heterogeneous catalysts. the combination of nanoparticles and ionic liquid fragments on the microsphere surfaces enhance the activity and durability of the catalyst. the pppil-pd-0 catalyst has been tested in the suzuki cross-coupling reaction, and exhibits much higher catalytic activity than pd catalysts supported on porous polymer matrices. the pppil.pd-0 catalyst can be recycled at least for nine runs without any significant loss of activity. tie present approach may, therefore, have potential applications in transition-metal-nanocatalyzed reactions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000275240300014 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43876]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li SH,Wang JH,Kou YL,et al. Ionic-Liquid-Grafted Rigid Poly (p-Phenylene) Microspheres: Efficient Heterogeneous Media for Metal Scavenging and Catalysis[J]. chemistry-a european journal,2010,16(6):1812-1818. |
| APA | Li SH,Wang JH,Kou YL,&Zhang SB.(2010).Ionic-Liquid-Grafted Rigid Poly (p-Phenylene) Microspheres: Efficient Heterogeneous Media for Metal Scavenging and Catalysis.chemistry-a european journal,16(6),1812-1818. |
| MLA | Li SH,et al."Ionic-Liquid-Grafted Rigid Poly (p-Phenylene) Microspheres: Efficient Heterogeneous Media for Metal Scavenging and Catalysis".chemistry-a european journal 16.6(2010):1812-1818. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。