Construction of Metal-Organic Frameworks with Tetranuclear Metal Clusters: Hydrothermal Synthesis, Structure, and Magnetic Properties
文献类型：期刊论文
| 作者 | Wang GH ; Lei YQ ; Wang N ; He RL ; Jia HQ ; Hu NH ; Xu JW |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2010 |
| 卷号 | 10期号:2页码:534-540 |
| 关键词 | SHAPED CARBOXYLATE LIGAND COORDINATION POLYMERS BUILDING-BLOCKS CRYSTAL-STRUCTURES GAS SORPTION DESIGN CHEMISTRY UNITS NETS ARCHITECTURES |
| ISSN号 | 1528-7483 |
| 通讯作者 | hu nh |
| 中文摘要 | five novel coordination polymers [co-4(oabdc)(2)(oh)(2)(h2o)(4)](n)center dot(h2o)(4.4n) (1), [ni-4(oabdc)(2)(oh)(2)(h2o)(4)](n)center dot(h2o)(4n) (2) (oabdc = 5-oxyacetateisophthalate), [co-2(oabdc)(bpe)(oh)](n)center dot(h2o)(2.9n) (3), [zn-2(oabdc)(bpe)(oh)](n)center dot(h2o)(3.5n) (4) (bpe = 1,2-bis(4-pyridyl)ethylene), and [co-2(oabdc)(bpy)(oh)](n)center dot(h2o)(2.2n) (5) (bpy = 4,4'-bipyridine) have been acquired at similar hydrothermal conditions. all compounds are constructed from tetranuclear [m-4(mu(3)-oh)(2)] (m = co for 1, 3, and 5, ni for 2, zn for 4) clusters. compounds 1 and 2 are isomorphous, in which the m-4(oh)(2) units act as 6-connected nodes and the frameworks are two-dimensional (2d) (3,6)-connected nets with the rare cdi2 type. if considering the strong h-bond interactions between neighboring layers, both exhibit three-dimensional (3d) microporous networks with channels running along the [100] direction. complexes 3 and 4 are also isomorphous, in which the 2d cdi2-based layer was pillared by bpe spacers; thus channels occur along the [100] direction. while adopting bpy instead of the bpe ligand, smaller channels are observed along the [100] direction for 5. the last three compounds all feature 3d networks with one of the scarce (3,8)-connected (4(3))(2)center dot(4(6)center dot 6(18)center dot 8(4)) topologies. magnetic susceptibility measurements indicate that compound 1 shows strong anti ferromagnetic behavior, while 2 exhibits strong ferromagnetic behavior. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000274837000012 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43888]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang GH,Lei YQ,Wang N,et al. Construction of Metal-Organic Frameworks with Tetranuclear Metal Clusters: Hydrothermal Synthesis, Structure, and Magnetic Properties[J]. crystal growth & design,2010,10(2):534-540. |
| APA | Wang GH.,Lei YQ.,Wang N.,He RL.,Jia HQ.,...&Xu JW.(2010).Construction of Metal-Organic Frameworks with Tetranuclear Metal Clusters: Hydrothermal Synthesis, Structure, and Magnetic Properties.crystal growth & design,10(2),534-540. |
| MLA | Wang GH,et al."Construction of Metal-Organic Frameworks with Tetranuclear Metal Clusters: Hydrothermal Synthesis, Structure, and Magnetic Properties".crystal growth & design 10.2(2010):534-540. |
入库方式： OAI收割
来源：长春应用化学研究所
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