Synthesis and characterization of hyperbranched polymers via Cp2TiCl-catalyzed self-condensing vinyl polymerization using glycidyl methacrylate as inimer
文献类型：期刊论文
| 作者 | Liu XH ; Dong ZM ; Tang XL ; Li YS |
| 刊名 | polymer
 |
| 出版日期 | 2010 |
| 卷号 | 51期号:4页码:854-859 |
| 关键词 | RADICAL STYRENE POLYMERIZATIONS RING-OPENING POLYMERIZATION ONE-POT SYNTHESIS BRANCHED POLY(N-ISOPROPYLACRYLAMIDE) RAFT POLYMERIZATION DIVINYL MONOMER STAR POLYMERS POLYSTYRENE COPOLYMERIZATION EPOXIDE |
| ISSN号 | 0032-3861 |
| 通讯作者 | li ys |
| 中文摘要 | hyperbranched polymers were produced using glycidyl methacrylate (gma)/cp2ticl2/zn as self-condensing vinyl polymerization (scvp) system. the polymerization is firstly initiated by the epoxide radical ring opening catalyzed by cp2ti(iii)cl generated in situ via the reaction of cp2ticl2 with zn. by optimizing the molar ratio of the scvp inimer (gma) to the mediator (cp2ti(iii)cl), the active propagation chains are reversibly transformed to the dormant species and the cross-linking does not occur until a higher level of monomer conversion (ca. 80%). we detail this facile one-step polymerization technique to prepare highly branched polymers with a multiplicity of particular end reactive functionalities including ti alkoxide, hydroxyl and vinyl functional groups, which differs from most previously reported scvp systems. (c) 2010 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000274679700005 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43906]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XH,Dong ZM,Tang XL,et al. Synthesis and characterization of hyperbranched polymers via Cp2TiCl-catalyzed self-condensing vinyl polymerization using glycidyl methacrylate as inimer[J]. polymer,2010,51(4):854-859. |
| APA | Liu XH,Dong ZM,Tang XL,&Li YS.(2010).Synthesis and characterization of hyperbranched polymers via Cp2TiCl-catalyzed self-condensing vinyl polymerization using glycidyl methacrylate as inimer.polymer,51(4),854-859. |
| MLA | Liu XH,et al."Synthesis and characterization of hyperbranched polymers via Cp2TiCl-catalyzed self-condensing vinyl polymerization using glycidyl methacrylate as inimer".polymer 51.4(2010):854-859. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。