Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and beta-Ga2O3:Dy3+
文献类型：期刊论文
| 作者 | Li GG ; Peng C ; Li CX ; Yang PAP ; Hou ZY ; Fan Y ; Cheng ZY ; Lin J |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 49期号:4页码:1449-1457 |
| 关键词 | GA2O3 THIN-FILMS GALLIUM OXIDE HYDROTHERMAL SYNTHESIS PHOTOLUMINESCENCE PROPERTIES YTTRIUM HYDROXIDE LARGE-SCALE NANORODS NANOTUBES NANOPARTICLES NANOCRYSTALS |
| ISSN号 | 0020-1669 |
| 通讯作者 | lin j |
| 中文摘要 | dy3+-doped gallium oxide hydroxides (gaooh:dy3+) with various morphologies (submicrospindles, submicroellipsoids, 3d hierarchical microspheres) were synthesized by a facile soft-chemical method. after annealing at 1000 degrees c, the gaooh:dy3+ precursor was easily converted to beta-ga2o3:dy3+ phosphors which kept their original morphologies. the as-prepared gaooh:dy3+ and beta-ga2o3:dy3+ products were characterized using x-ray diffraction (xrd), field-emission scanning electron microscopy (fesem), low- to high-resolution transmission electron microscopy (tem), selected area electron diffraction (saed), photoluminescence (pl) spectra, cathodoluminescence (cl) spectra, and quantum yield (qy). with an increase in ph from 4 to 9, the morphology of gaooh:dy3+ varied from submicrospindles to 3d hierarchical microspheres of self-assembled nanoparticles. a possible mechanism for the formation of various morphologies of gaooh:dy3+ and beta-ga2o3:dy3+ was proposed. under ultraviolet and low-voltage electron beam excitation, the pure beta-ga2o3 samples exhibit a blue emission with a maximum at 438 nm originating from the gao6 groups, while the beta-ga2o3:dy3+ samples show the characteristic emission of dy3+ corresponding to f-4(9/2) -> h-6(15/2), (13/2) transitions due to an efficient energy transfer from beta-ga2o3 to dy3+. a simple model was proposed to explain the energy transfer process and luminescence mechanism. furthermore, the dependence of luminescence intensity on the morphology has been investigated in detail. under 257 nm uv and electron beam excitation, the beta-ga2o3:dy3+ phosphor with a submicroellipsoid shape shows the highest relative emission intensity and quantum yield compared with other morphologies, and the obtained phosphors have potential applications in the areas of fluorescent lamps and field emission displays (feds). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000274240700032 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43936]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li GG,Peng C,Li CX,et al. Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and beta-Ga2O3:Dy3+[J]. inorganic chemistry,2010,49(4):1449-1457. |
| APA | Li GG.,Peng C.,Li CX.,Yang PAP.,Hou ZY.,...&Lin J.(2010).Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and beta-Ga2O3:Dy3+.inorganic chemistry,49(4),1449-1457. |
| MLA | Li GG,et al."Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and beta-Ga2O3:Dy3+".inorganic chemistry 49.4(2010):1449-1457. |
入库方式： OAI收割
来源：长春应用化学研究所
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