One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene
文献类型:期刊论文
作者 | Cao F ; Liu RX ; Zhou L ; Song SY ; Lei YQ ; Shi WD ; Zhao FY ; Zhang HJ |
刊名 | journal of materials chemistry
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出版日期 | 2010 |
卷号 | 20期号:6页码:1078-1085 |
关键词 | GAS-PHASE HYDROGENATION HYDROTHERMAL SYNTHESIS CONTROLLABLE SYNTHESIS ORIENTED AGGREGATION TRANSPORT-PROPERTIES PALLADIUM CATALYSTS NITRO-COMPOUNDS LOW-TEMPERATURE MOS2 CATALYSTS HOLLOW SPHERES |
ISSN号 | 0959-9428 |
通讯作者 | zhang hj |
中文摘要 | uniform flowerlike ni7s6 nanostructures composed of nanopetals with sharp tips have been synthesized by a mild hydrothermal method. on the basis of a series of contrast experiments, a probable growth mechanism and fabrication process of the flowerlike products was proposed. the catalytic performances of the as-synthesized samples were tested in selective hydrogenation of chloronitrobezene. compared with other nickel sulfide samples with different morphologies and structures, flowerlike ni7s6 samples show much higher activity and selectivity in the hydrogenations of nitrobenzene and chloronitrobenzenes with different chlorine substituent site. to the best of our knowledge, this is the first time that uniform flower-like ni7s6 with high selectivity to nitro group have been synthesized in solution. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000273961900007 |
公开日期 | 2012-06-07 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43955] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Cao F,Liu RX,Zhou L,et al. One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene[J]. journal of materials chemistry,2010,20(6):1078-1085. |
APA | Cao F.,Liu RX.,Zhou L.,Song SY.,Lei YQ.,...&Zhang HJ.(2010).One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene.journal of materials chemistry,20(6),1078-1085. |
MLA | Cao F,et al."One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene".journal of materials chemistry 20.6(2010):1078-1085. |
入库方式: OAI收割
来源:长春应用化学研究所
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