Conjugated Copolymers Comprised Cyanophenyl-Substituted Spirobifluorene and Tricarbazole-Triphenylamine Repeat Units for Blue-Light-Emitting Diodes
文献类型：期刊论文
| 作者 | Lin Y ; Chen ZK ; Ye TL ; Dai YF ; Ma DG ; Ma Z ; Liu QD ; Chen Y |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 48期号:2页码:292-301 |
| 关键词 | HIGHLY EFFICIENT PHOTOVOLTAIC DEVICES OPTOELECTRONIC PROPERTIES IRIDIUM COMPLEXES SINGLE POLYMER PENDANT GROUPS SOLAR-CELLS GREEN-LIGHT POLYFLUORENE FLUORENE |
| ISSN号 | 0887-624x |
| 通讯作者 | chen zk |
| 中文摘要 | a series of conjugated blue-light-emitting copolymers, ptc-1, ptc-2, and ptc-3, comprised different ratios of electron-withdrawing segments (spirobifluorene substituted with cyanophenyl groups) and electron-donating segments (tricarbazole-triphenylamines), has been synthesized. the structures of these polymers were characterized and their thermal, photophysical, electrochemical, and electroluminescence properties were measured. incorporation of rigid spirobifluorene units into the copolymers led to blue-shifted absorption peaks in dilute toluene solution. cyclic voltammetric measurement indicated the bandgaps of the polymers were in the range of 2.77-2.94 ev. it was found that increasing cyanophenyl-spirobifluorene content in the polymer backbone lowered both the homo and lumo energy levels of the copolymers, which was beneficial for electron injection/transporting in the polymer layer of the device. oled device evaluation indicated that all the polymers emitted sky blue to deep blue light when the pure polymers were used as the emissive layers in the devices with a configuration of ito/pedot:pss/polymers/csf/ca/al. the devices have been optimized by doping 30 wt % pbd into the polymer layers. among the doped devices, ptc-2 showed the best performance with the turn-on voltage of 3.0 v, maximum brightness of 7257 cd/m(2), maximum current efficiency of 1.76 cd/a, and cie coordinates of (0.15, 0.14). (c) 2009 wiley periodicals, inc. j polym sci part a: polym chem 48: 292-301, 2010 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000273581700003 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43975]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin Y,Chen ZK,Ye TL,et al. Conjugated Copolymers Comprised Cyanophenyl-Substituted Spirobifluorene and Tricarbazole-Triphenylamine Repeat Units for Blue-Light-Emitting Diodes[J]. journal of polymer science part a-polymer chemistry,2010,48(2):292-301. |
| APA | Lin Y.,Chen ZK.,Ye TL.,Dai YF.,Ma DG.,...&Chen Y.(2010).Conjugated Copolymers Comprised Cyanophenyl-Substituted Spirobifluorene and Tricarbazole-Triphenylamine Repeat Units for Blue-Light-Emitting Diodes.journal of polymer science part a-polymer chemistry,48(2),292-301. |
| MLA | Lin Y,et al."Conjugated Copolymers Comprised Cyanophenyl-Substituted Spirobifluorene and Tricarbazole-Triphenylamine Repeat Units for Blue-Light-Emitting Diodes".journal of polymer science part a-polymer chemistry 48.2(2010):292-301. |
入库方式： OAI收割
来源：长春应用化学研究所
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