Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection
文献类型：期刊论文
| 作者 | Yuan BQ ; Zheng CY ; Teng H ; You TY |
| 刊名 | journal of chromatography a
 |
| 出版日期 | 2010 |
| 卷号 | 1217期号:1页码:171-174 |
| 关键词 | ZONE-ELECTROPHORESIS TROPANE ALKALOIDS FLOS-DATURAE HYOSCYAMUS-MUTICUS SEPARATION CHROMATOGRAPHY URINE DRUGS ASSAY |
| ISSN号 | 0021-9673 |
| 通讯作者 | you ty |
| 中文摘要 | a rapid and simple method was demonstrated for the analysis of atropine, anisodamine, and scopolamine by nonaqueous capillary electrophoresis (nace) coupled with electrochemiluminescence (ecl) and electrochemistry (ec) dual detection. the mixture of acetonitrile (acn) and 2-propanol containing 1 m acetic acid (hac), 20 mm sodium acetate (naac), and 2.5 mm tetrabutylammonium perchlorate (tbap) was used as the electrophoretic buffer. although a short capillary of 18 cm was used, the decoupler was not needed and the separation efficiency was good. the linear ranges of atropine, anisodamine, and scopolamine were 0.5-50, 5-2000, and 50-2000 mu m, respectively. for six replicate measurements of 100 mu m scopolamine, 15 mu m atropine, and 200 mu m anisodamine, the rsds of ecl intensity, ec current, and migration time were less than 3.6%, 4.5%. and 0.3%, respectively. in addition, because the organic buffer was used, the working electrode (pt) was not easily fouled and did not need reactivation. the method was also applied for the determination of these three alkaloids in flos daturae extract. (c) 2009 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000273623100023 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43981]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan BQ,Zheng CY,Teng H,et al. Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection[J]. journal of chromatography a,2010,1217(1):171-174. |
| APA | Yuan BQ,Zheng CY,Teng H,&You TY.(2010).Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection.journal of chromatography a,1217(1),171-174. |
| MLA | Yuan BQ,et al."Simultaneous determination of atropine, anisodamine, and scopolamine in plant extract by nonaqueous capillary electrophoresis coupled with electrochemiluminescence and electrochemistry dual detection".journal of chromatography a 1217.1(2010):171-174. |
入库方式： OAI收割
来源：长春应用化学研究所
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