Combination of on-line preconcentration by di(2-ethylhexyl) phosphoric acid resin in the presence of complexing agent with microwave plasma-atomic emission spectrometry for the determination of rare earths
文献类型:期刊论文
作者 | Zhao XW ; Kong XF ; Jia QO ; Zhou WH ; Qu XG |
刊名 | journal of rare earths
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出版日期 | 2010 |
卷号 | 28期号:增刊页码:79-82 |
关键词 | LIQUID-LIQUID-EXTRACTION SELECTIVE SEPARATION NONEQUILIBRIUM EXTRACTION YTTRIUM IONS ELEMENTS SYSTEMS METALS CA-100 |
ISSN号 | 1002-0721 |
通讯作者 | jia qo |
中文摘要 | the adsorption of rare earths, lanthanum, cerium, neodymium, and yttrium by di(2-ethylhexyl) phosphoric acid (d2ehpa) resin in the presence of a complexing agent, edta, was investigated. flow injection was selected as the injecting method. various parameters, sample ph, sample loading time, sample flow rate, edta concentration, edta flow rate, eluent concentration, and eluent flow rate, were studied and optimized. under the optimum conditions, the method allowed the determination of rare earths with detection limits of 1.09 mu g/l (lanthanum), 3.31 mu g/l (cerium), 2.05 mu g/l (neodymium), and 1.25 mu g/l (yttrium). high repeatabilities were obtained for all the four rare earths (rsd<5%). the proposed method was applied to the determination of the rare earths in water samples with a recovery range of 95.8%-103.3%. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000287023600013 |
公开日期 | 2012-06-07 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44008] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhao XW,Kong XF,Jia QO,et al. Combination of on-line preconcentration by di(2-ethylhexyl) phosphoric acid resin in the presence of complexing agent with microwave plasma-atomic emission spectrometry for the determination of rare earths[J]. journal of rare earths,2010,28(增刊):79-82. |
APA | Zhao XW,Kong XF,Jia QO,Zhou WH,&Qu XG.(2010).Combination of on-line preconcentration by di(2-ethylhexyl) phosphoric acid resin in the presence of complexing agent with microwave plasma-atomic emission spectrometry for the determination of rare earths.journal of rare earths,28(增刊),79-82. |
MLA | Zhao XW,et al."Combination of on-line preconcentration by di(2-ethylhexyl) phosphoric acid resin in the presence of complexing agent with microwave plasma-atomic emission spectrometry for the determination of rare earths".journal of rare earths 28.增刊(2010):79-82. |
入库方式: OAI收割
来源:长春应用化学研究所
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