Adsorption of phenol from water by N-butylimidazolium functionalized strongly basic anion exchange resin
文献类型:期刊论文
作者 | Zhu LL ; Deng YF ; Zhang JP ; Chen J |
刊名 | journal of colloid and interface science
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出版日期 | 2011 |
卷号 | 364期号:2页码:462-468 |
关键词 | AQUEOUS-SOLUTIONS ACTIVATED-SLUDGE POLYMERIC ADSORBENT IONIC LIQUIDS REMOVAL BIOSORPTION EXTRACTION CHLOROPHENOLS CHROMIUM(VI) EQUILIBRIUM |
ISSN号 | 0021-9797 |
通讯作者 | chen j |
中文摘要 | n-butylimidazolium functionalized strongly basic anion exchange resin with cl(-) anion (mcl) was prepared by anchoring n-butylimidazole onto chloromethylated macroporous styrene-divinylbenzene (st-dvb) copolymer. the adsorption performances of phenol on mcl were studied using the batch technique at acidic and alkaline ph. the studies showed that phenol can be effectively removed at both acidic and alkaline ph. the maximum adsorption was achieved at about ph 11. the maximum adsorption capacities of phenol on mcl at ph 6.6 and 11.2 were 80.2 and 92.9 mg/g, respectively. the adsorption mechanism was mainly molecular adsorption at acidic ph and anion exchange at alkaline ph. the adsorption of phenol was hindered by the presence of cl(-) and so(4)(2-) at alkaline ph due to the competitive anion exchange reaction. the adsorption of molecular phenol species on mcl at acidic ph was exothermic, and the anion exchange of phenolate species by mcl at alkaline ph was endothermic. desorption of phenol from loaded adsorbent was achieved by using 0.5 mol/l naoh and 0.5 mol/l nacl mixed solution. mcl can simultaneously remove phenol and cr(vi) from their mixtures, which would be of practical value in actual industrial wastewater treatment. (c) 2011 elsevier inc. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000296223500025 |
公开日期 | 2012-06-07 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44176] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhu LL,Deng YF,Zhang JP,et al. Adsorption of phenol from water by N-butylimidazolium functionalized strongly basic anion exchange resin[J]. journal of colloid and interface science,2011,364(2):462-468. |
APA | Zhu LL,Deng YF,Zhang JP,&Chen J.(2011).Adsorption of phenol from water by N-butylimidazolium functionalized strongly basic anion exchange resin.journal of colloid and interface science,364(2),462-468. |
MLA | Zhu LL,et al."Adsorption of phenol from water by N-butylimidazolium functionalized strongly basic anion exchange resin".journal of colloid and interface science 364.2(2011):462-468. |
入库方式: OAI收割
来源:长春应用化学研究所
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