Fabrication of an electrochemical platform based on the self-assembly of graphene oxide-multiwall carbon nanotube nanocomposite and horseradish peroxidase: direct electrochemistry and electrocatalysis
文献类型:期刊论文
作者 | Zhang Q ; Yang SJ ; Zhang J ; Zhang L ; Kang PL ; Li JH ; Xu JW ; Zhou H ; Song XM |
刊名 | nanotechnology
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出版日期 | 2011 |
卷号 | 22期号:49页码:1-7 |
关键词 | HEMOGLOBIN BIOELECTROCHEMISTRY IMMOBILIZATION BIOSENSORS NANOSHEETS MYOGLOBIN |
ISSN号 | 0957-4484 |
通讯作者 | li jh |
中文摘要 | a novel hybrid nanomaterial (go-mwnts) was explored based on the self-assembly of multiwall carbon nanotubes (mwnts) and graphene oxide (go). compared with pristine mwnts, such a nanocomposite could be well dispersed in aqueous solution and exhibit a negative charge. driven by the electrostatic interaction, positively charged horseradish peroxidase (hrp) could then be immobilized onto go-mwnts at the surface of a glassy carbon (gc) electrode to form a hrp/go-mwnt/gc electrode under mild conditions. tem was used to characterize the morphology of the go-mwnt nanocomposite. uv-vis and ftir spectra suggested that hrp was immobilized onto the hybrid matrix without denaturation. furthermore, the immobilized hrp showed enhanced direct electron transfer for the hrp-fe(iii)/fe(ii) redox center. based on the direct electron transfer of the immobilized hrp, the hrp/go-mwnt/gc electrode exhibited excellent electrocatalytic behavior to the reduction of h(2)o(2) and nano(2), respectively. therefore, go-mwnts could provide a novel and efficient platform for the immobilization and biosensing of redox enzymes, and thus may find wide potential applications in the fabrication of biosensors, biomedical devices, and bioelectronics. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000297370700011 |
公开日期 | 2012-06-07 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44178] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang Q,Yang SJ,Zhang J,et al. Fabrication of an electrochemical platform based on the self-assembly of graphene oxide-multiwall carbon nanotube nanocomposite and horseradish peroxidase: direct electrochemistry and electrocatalysis[J]. nanotechnology,2011,22(49):1-7. |
APA | Zhang Q.,Yang SJ.,Zhang J.,Zhang L.,Kang PL.,...&Song XM.(2011).Fabrication of an electrochemical platform based on the self-assembly of graphene oxide-multiwall carbon nanotube nanocomposite and horseradish peroxidase: direct electrochemistry and electrocatalysis.nanotechnology,22(49),1-7. |
MLA | Zhang Q,et al."Fabrication of an electrochemical platform based on the self-assembly of graphene oxide-multiwall carbon nanotube nanocomposite and horseradish peroxidase: direct electrochemistry and electrocatalysis".nanotechnology 22.49(2011):1-7. |
入库方式: OAI收割
来源:长春应用化学研究所
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