M0.5C11H12N2O2 (M = Zn, Co, Ni): A Two-dimensional Layered Hybrid Compound Derived from L-Tryptophan Containing Helical Chains
文献类型：期刊论文
| 作者 | Shen S ; Zhao L |
| 刊名 | zeitschrift fur anorganische und allgemeine chemie
 |
| 出版日期 | 2011 |
| 卷号 | 637期号:14-15页码:2099-2102 |
| 关键词 | METAL COORDINATION POLYMERS CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS MAGNETIC-PROPERTIES BUILDING UNITS FRAMEWORK CHANNELS ZINC FLUORESCENCE ASPARTATE |
| ISSN号 | 0044-2313 |
| 通讯作者 | zhao l |
| 中文摘要 | a series of two-dimensional (2d) layered transition metal coordination polymers, m0.5c11h12n2o2 [m = zn (1), co (2), ni (3)], were synthesized under hydrothermal conditions with biological amino acid d,l-tryptophan molecules as ligands. the crystal structures of all compounds were isomorphous. compounds 13 were characterized by inductively coupled plasma mass spectrometry (icp-ms), elemental analysis, powder x-ray diffraction, thermogravimetric analysis, and fluorescence spectroscopy, as well as single-crystal x-ray diffraction analysis. only the structure of compound 1 is discussed in detail. it crystallizes in the monoclinic system, space group p21/c (no.14), a = 19.778(4) angstrom, b = 5.3988 angstrom, c = 9.2837 angstrom, beta = 97.13(3)degrees, v = 983.6(3) angstrom 3, and z = 4. in its structure, each zinc atom is octahedrally coordinated to four tryptophan ligands that are bonded to the zinc atom in a tridentate fashion through one znn(-nh2) and two zno(coo) bonds. furthermore, compound 1 exhibits solid state fluorescence emission maxima at 340 and 420 nm, compound 2 at 340, 422, 485 nm, and compound 3 at 337, 424, 488 nm upon excitation at 295 nm. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000298478600005 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44186]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Shen S,Zhao L. M0.5C11H12N2O2 (M = Zn, Co, Ni): A Two-dimensional Layered Hybrid Compound Derived from L-Tryptophan Containing Helical Chains[J]. zeitschrift fur anorganische und allgemeine chemie,2011,637(14-15):2099-2102. |
| APA | Shen S,&Zhao L.(2011).M0.5C11H12N2O2 (M = Zn, Co, Ni): A Two-dimensional Layered Hybrid Compound Derived from L-Tryptophan Containing Helical Chains.zeitschrift fur anorganische und allgemeine chemie,637(14-15),2099-2102. |
| MLA | Shen S,et al."M0.5C11H12N2O2 (M = Zn, Co, Ni): A Two-dimensional Layered Hybrid Compound Derived from L-Tryptophan Containing Helical Chains".zeitschrift fur anorganische und allgemeine chemie 637.14-15(2011):2099-2102. |
入库方式： OAI收割
来源：长春应用化学研究所
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