Syntheses, Crystal Structures, and Magnetic Properties of mu-O/mu-Cl Bridged Dinuclear Manganese(II) and Copper(II) Complexes with Schiff base Ligand HL [HL=2-(benzothiazol-2-yl-hydrazonomethyl)-6-methoxyphenol]
文献类型：期刊论文
| 作者 | Gao YJ ; Ji YF ; Ding S ; Liu ZL ; Tang JK |
| 刊名 | zeitschrift fur anorganische und allgemeine chemie
 |
| 出版日期 | 2011 |
| 卷号 | 637期号:14-15页码:2300-2305 |
| 关键词 | BINUCLEAR COMPLEXES METAL-COMPLEXES ACTIVE-SITE COORDINATION CHEMISTRY MN(II) COMPLEXES N-OXIDE NICKEL(II) CLUSTER PHENOL ANTIBACTERIAL |
| ISSN号 | 0044-2313 |
| 通讯作者 | liu zl |
| 中文摘要 | a novel versatile multidentate ligand 2-(benzothiazol-2-yl-hydrazonomethyl)-6-methoxyphenol (hl), was obtained from a condensation reaction between 2-hydrazino benzothiazole and o-vanillin. the reactions of hl with cucl2 center dot 2h2o/mn(clo4)2 center dot 6h2o generated two novel dinuclear compounds cu2l(mu-cl)cl2(ch3oh)2 (1) and mn2l3(clo4)(ch3ch2oh)3 (2). the crystal structures of 1 and 2 were determined by x-ray diffraction studies. the two copper atoms in complex 1 are connected by a l anion and a single chloro bridge with a cu center dot center dot center dot cu separation of 3.2729(4) angstrom. in complex 2, the two manganese atoms are held together by two l anion bridges and the mn center dot center dot center dot mn separation amounts to 3.3433(7) angstrom. as expected, variable-temperature magnetic susceptibility measurements of complex 1 showed strong antiferromagnetic intramolecular coupling between the copper(ii) atoms with j = 102.2 cm1, and evidenced for complex 2 weak antiferromagnetic coupling with j = 1.68 cm1. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000298478600038 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44187]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao YJ,Ji YF,Ding S,et al. Syntheses, Crystal Structures, and Magnetic Properties of mu-O/mu-Cl Bridged Dinuclear Manganese(II) and Copper(II) Complexes with Schiff base Ligand HL [HL=2-(benzothiazol-2-yl-hydrazonomethyl)-6-methoxyphenol][J]. zeitschrift fur anorganische und allgemeine chemie,2011,637(14-15):2300-2305. |
| APA | Gao YJ,Ji YF,Ding S,Liu ZL,&Tang JK.(2011).Syntheses, Crystal Structures, and Magnetic Properties of mu-O/mu-Cl Bridged Dinuclear Manganese(II) and Copper(II) Complexes with Schiff base Ligand HL [HL=2-(benzothiazol-2-yl-hydrazonomethyl)-6-methoxyphenol].zeitschrift fur anorganische und allgemeine chemie,637(14-15),2300-2305. |
| MLA | Gao YJ,et al."Syntheses, Crystal Structures, and Magnetic Properties of mu-O/mu-Cl Bridged Dinuclear Manganese(II) and Copper(II) Complexes with Schiff base Ligand HL [HL=2-(benzothiazol-2-yl-hydrazonomethyl)-6-methoxyphenol]".zeitschrift fur anorganische und allgemeine chemie 637.14-15(2011):2300-2305. |
入库方式： OAI收割
来源：长春应用化学研究所
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