Synthesis, characterization, and aqueous solution behavior of copolymers of acrylamide and sodium 10-acryloyloxydecanoate
文献类型：期刊论文
| 作者 | Song CL ; An HY ; Yang QB ; Li WB ; Liu C ; Wang PX |
| 刊名 | polymer bulletin
 |
| 出版日期 | 2011 |
| 卷号 | 67期号:9页码:1917-1934 |
| ISSN号 | 0170-0839 |
| 关键词 | WATER-SOLUBLE COPOLYMERS ASSOCIATING POLYACRYLAMIDES POLYMERS POLYELECTROLYTES PH TERPOLYMERS SYSTEMS 3-ACRYLAMIDO-3-METHYLBUTANOATE VISCOSITY MONOMERS |
| 通讯作者 | song cl |
| 中文摘要 | a new water-soluble monomer of sodium 10-acryloyloxydecanoate (naad), which possesses a hydrophobic group and an ionizable group, was synthesized from acryloyl chloride and 10-hydroxydecanoic acid, and the series of copolymers of naad with acrylamide (am) were prepared by the free radical polymerization in aqueous solution using ammonium persulfate as the initiator. the feed ratio of naad:am was varied from 5:95 to 70:30 mol%, with the total monomer concentration held constant at 0.5 m. the copolymer compositions were determined from elemental analysis. the molecular weights of the copolymers were determined by gel permeation chromatography ranged from 0.76 x 10(6) to 1.37 x 10(6) g/mol. all copolymers were soluble in deionized water and salt solutions at ph > 5. the dilute and semidilute solution behavior of the copolymers was studied as a function of composition, ph, and added electrolytes, and the results indicated that naad30 exhibited much higher viscosity values. at moderate ph values, the copolymers coils become slightly more expanded and intermolecular association interactions occur, which was indicated by fluorescence and apparent viscosity measurements. upon the addition of nacl and in low ph, viscosities tended to decrease because of the disruption of the intermolecular associations. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000296732500016 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44204]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Song CL,An HY,Yang QB,et al. Synthesis, characterization, and aqueous solution behavior of copolymers of acrylamide and sodium 10-acryloyloxydecanoate[J]. polymer bulletin,2011,67(9):1917-1934. |
| APA | Song CL,An HY,Yang QB,Li WB,Liu C,&Wang PX.(2011).Synthesis, characterization, and aqueous solution behavior of copolymers of acrylamide and sodium 10-acryloyloxydecanoate.polymer bulletin,67(9),1917-1934. |
| MLA | Song CL,et al."Synthesis, characterization, and aqueous solution behavior of copolymers of acrylamide and sodium 10-acryloyloxydecanoate".polymer bulletin 67.9(2011):1917-1934. |
入库方式： OAI收割
来源：长春应用化学研究所
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