Utilization of (oxalato)borate-based organic electrolytes in activated carbon/graphite capacitors
文献类型：期刊论文
| 作者 | Wang YX ; Zheng C ; Qi L ; Yoshio M ; Yoshizuka K ; Wang HY |
| 刊名 | journal of power sources
 |
| 出版日期 | 2011 |
| 卷号 | 196期号:23页码:10507-10510 |
| 关键词 | DOUBLE-LAYER CAPACITOR QUATERNARY AMMONIUM-SALTS ELECTROCHEMICAL CAPACITORS ION SIZE CARBON PERFORMANCE AC/GRAPHITE |
| ISSN号 | 0378-7753 |
| 通讯作者 | wang hy |
| 中文摘要 | the electrolyte salts composed of tetramethylammonium (tma(+)) cation and difluoro(oxalato)borate (dfob(-)) or bis(oxalato)borate (bob(-)) anions have been proposed for the application in activated carbon (ac)/graphite capacitors. the electrochemical performance of ac/graphite capacitors has been studied using these electrolyte salts dissolved in propylene carbonate (pc). the intercalation behaviors of anions (bf(4)(-), dfob(-), and bob(-)) at the graphite positive electrodes have been investigated by in situ xrd measurements. the bigger the anion is, the higher the cell voltage is where the intercalation happens. accordingly, the bigger the anion is, the smaller discharge capacity delivered by an ac/graphite capacitor. the charge mechanism of tma(+) at the ac negative side has also been addressed. compared with other bigger quaternary alkyl ammonium cations, the specific capacitance of the ac negative electrode towards tma(+) adsorption is somehow smaller as estimated. (c) 2011 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000296216600090 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44206]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang YX,Zheng C,Qi L,et al. Utilization of (oxalato)borate-based organic electrolytes in activated carbon/graphite capacitors[J]. journal of power sources,2011,196(23):10507-10510. |
| APA | Wang YX,Zheng C,Qi L,Yoshio M,Yoshizuka K,&Wang HY.(2011).Utilization of (oxalato)borate-based organic electrolytes in activated carbon/graphite capacitors.journal of power sources,196(23),10507-10510. |
| MLA | Wang YX,et al."Utilization of (oxalato)borate-based organic electrolytes in activated carbon/graphite capacitors".journal of power sources 196.23(2011):10507-10510. |
入库方式： OAI收割
来源：长春应用化学研究所
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