Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization
文献类型：期刊论文
| 作者 | Xiao TPF ; Zhang S ; Li BX ; Hao X ; Redshaw C ; Li YS ; Sun WH |
| 刊名 | polymer
 |
| 出版日期 | 2011 |
| 卷号 | 52期号:25页码:5803-5810 |
| 关键词 | TRIDENTATE BIS(IMINO)PYRIDINE COMPLEXES 2 HIGH-TEMPERATURE CATALYSTS 6-BIS(IMINO)PYRIDYL IRON HIGHLY-ACTIVE CATALYSTS OLEFIN POLYMERIZATION ALPHA-OLEFINS STRUCTURAL-CHARACTERIZATION ELECTRONIC-STRUCTURES DIIMINE COMPLEXES METAL FE |
| ISSN号 | 0032-3861 |
| 通讯作者 | sun wh |
| 中文摘要 | the series of ligands 2-(1-(arylimino)methyl)-8-(1h-benzimidazol-2-yl)quinolines was synthesized and used to prepare new iron(ii) and cobalt(ii) dichloride complexes. x-ray diffraction studies revealed that the coordination geometry around the metal center can best be described as distorted square-based pyramidal. upon activation with methylaluminoxane (mao), both families (fe and co) of complexes showed good activities in ethylene polymerization, affording highly linear polyethylenes. enhanced activities were observed on increasing the reaction temperature to 100 degrees c. the optimization of the reaction parameters and the influence of the substituents on the imino-bound aryl group of the chelate ligands were investigated. (c) 2011 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000297539000015 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44212]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xiao TPF,Zhang S,Li BX,et al. Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization[J]. polymer,2011,52(25):5803-5810. |
| APA | Xiao TPF.,Zhang S.,Li BX.,Hao X.,Redshaw C.,...&Sun WH.(2011).Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization.polymer,52(25),5803-5810. |
| MLA | Xiao TPF,et al."Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization".polymer 52.25(2011):5803-5810. |
入库方式： OAI收割
来源：长春应用化学研究所
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