Monte Carlo Simulation of the Self-assembly of Amphiphilic Triblock Copolymer in Binary Block-Selective Solvents
文献类型：期刊论文
| 作者 | Fan JJ ; Han YY ; Jiang W |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 2011 |
| 卷号 | 69期号:19页码:2341-2346 |
| 关键词 | MORPHOLOGICAL TRANSITIONS DIBLOCK COPOLYMERS AQUEOUS-SOLUTIONS VESICLE FORMATION DILUTE-SOLUTION BEHAVIOR PEO |
| ISSN号 | 0567-7351 |
| 通讯作者 | fan jj |
| 中文摘要 | the effect of binary block-selective solvents on the self-assembly of aba amphiphilic triblock copolymer in dilute solution was studied by means of monte carlo study. the simulative results showed that the proportion of the binary block-selective solvents is one of the key factors that determines the morphologies of the copolymer aggregates. the morphologies formed by aba amphiphilic triblock copolymers changed from vesicle to lamella, ring, rod, and then to spheres by changing the proportion of binary solvent mixtures. the results revealed that changing the proportion of binary solvent mixtures and adjusting core-solvent interaction of single solvent had an equivalent effect on the self-assembled structure for the aba amphiphilic triblock copolymers. moreover, the dynamical pathways leading to ring and vesicle are analyzed in detail. it was found that the oblate membranes closed up to form vesicles, while the oblate membranes dissolved a hole to form ring. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000296933700022 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44289]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fan JJ,Han YY,Jiang W. Monte Carlo Simulation of the Self-assembly of Amphiphilic Triblock Copolymer in Binary Block-Selective Solvents[J]. acta chimica sinica,2011,69(19):2341-2346. |
| APA | Fan JJ,Han YY,&Jiang W.(2011).Monte Carlo Simulation of the Self-assembly of Amphiphilic Triblock Copolymer in Binary Block-Selective Solvents.acta chimica sinica,69(19),2341-2346. |
| MLA | Fan JJ,et al."Monte Carlo Simulation of the Self-assembly of Amphiphilic Triblock Copolymer in Binary Block-Selective Solvents".acta chimica sinica 69.19(2011):2341-2346. |
入库方式： OAI收割
来源：长春应用化学研究所
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